The continuous demand for novel hybrid materials in specific technological applications
inspires people to develop new synthetic strategies in a modular and efficient way. In the …

Although known for more than 40 years in the polymer chemistry field, the photochemical
radical thiol–ene addition (PRTEA) has been recently recognized as a chemical reaction …

Tetra (3-mercaptopropyl)-silsesquioxanes with double-decker (DDSQ) or ladder nano-cores
were easily prepared from the corresponding tetraallyl derivatives through fast and …

TPU/MVQ blends are widely used in biomedical electronic equipment, intelligent wearable
materials, and other fields. As they are immiscible systems, compatibilization of TPU/MVQ …

This article presents the synthesis of new derivatives of octa (3‐thiopropyl) silsesquioxane
(SSQ‐8SH) via thiol‐ene reaction with simple olefins bearing alkyl groups as well as …

In this work, new partially substituted derivatives of octa (3-thiopropyl) silsesquioxane (SSQ-
8SH) were synthesized. The article compares the thiol-ene reaction using two methods …

Here, we demonstrate a convenient and robust method for fabricating a series of dual-
functionalized silsesquioxane nanoparticles (SQ-NPs) using a thiol–epoxy click reaction and …

The structure and electronic properties of polyhedral oligomeric silsesquioxane (POSS)
cages functionalized with mono-substituted and multi-substituted vinyl and mercaptopropyl …

Abstract Here, high purity octa (3-mercaptopropyl) POSS has been synthesized and
subsequently reacted with a variety of alkenes via radical and base catalyzed thiol-ene …

The synthesis of octa (3-mercaptopropyl) octasilsesquioxane (γ HS-POSS) was studied with
a special regard to factors determining the yield of octahedral product (acidity of the reaction …