Excited (triplet) states offer a myriad of attractive synthetic pathways, including
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …

The concept of strain in organic compounds is as old as modern organic chemistry and was
initially introduced to justify the synthetic setbacks along the synthesis of small ring systems …

Dearomative photocycloadditions are valuable chemical transformations, serving as an
efficient platform to create three-dimensional molecular complexity. However, the …

Photocycloaddition is a powerful reaction to enable the conversion of alkenes into high-
value synthetic materials that are normally difficult to obtain under thermal conditions …

Cyclopropanes bearing contiguous all-carbon quaternary centers continue to attract
attention due to their bioactivities. However, methods to obtain cyclopropanes with …

Photochemical dearomative cycloaddition has emerged as a useful strategy to rapidly
generate molecular complexity. Within this context, stereo-and regiocontrolled …

Dearomatization of pyridines is a well-established synthetic approach to access piperidines.
Although remarkably powerful, existing dearomatization processes have been limited to the …

Controlling the ambident reactivity of thiocyanates in reaction manifolds has been a long-
standing and formidable challenge. We report herein a photoredox strategy for installing …

Heterocycles are the backbone of modern medical chemistry and drug development. The
derivatization of “an olefin” inside aromatic rings represents an ideal approach to access …

A novel and convenient approach that combines high‐throughput experimentation (HTE)
with machine learning (ML) technologies to achieve the first selective cross‐dimerization of …