The combination of metal-, photo-, enzyme-, and/or organocatalysis provides multiple
synthetic solutions, especially when the creation of chiral centers is involved. Historically …

The allene functionality has participated in one of the most exciting voyages in organic
chemistry, from chemical curiosities to a recurring building block in modern organic …

Herein we disclose an iron‐catalyzed cross‐coupling reaction of propargyl ethers with
Grignard reagents. The reaction was demonstrated to be stereospecific and allows for a …

A manganese (I)/Lewis acid cocatalyzed direct C− H propargylation with high selectivity has
been developed. BPh3 was discovered to not only promote the reactivity, but also enhance …

During the last decade, the combination of different metal-and bio-catalyzed organic
reactions in aqueous media has permitted the flourishing of a variety of one-pot asymmetric …

Transition metal catalysis in modern organic synthesis has largely focused on noble
transition metals like palladium, platinum and ruthenium. The toxicity and low abundance of …

Classical Crabbé type SN2'substitutions of propargylic substrates has served as one of the
standard methods for the synthesis of allenes. However, the stereospecific version of this …

The self-assembly of styrene-type olefins into the corresponding stilbenes was conveniently
performed in the Deep Eutectic Solvent (DES) mixture 1 ChCl/2 Gly under air and in the …

Abstract (Cyclopentadienone) iron tricarbonyl complexes are catalytically active,
inexpensive, easily accessible and air‐stable that are extensively studied as an active pre …

Abstract An enantioselective PdII/Brønsted acid‐catalyzed carbonylative carbocyclization of
enallenes ending with a cross‐dehydrogenative coupling (CDC) with a terminal alkyne was …