Cuprophilic interactions in and between molecular entities

NVS Harisomayajula, S Makovetskyi… - Chemistry–A European …, 2019 - Wiley Online Library
Despite being weak attractive forces, closed‐shell metallophilic interactions play important
roles in the Group 11 metal complexes on their diverse structural and physical features. A …

[HTML][HTML] Luminescent Copper (I) complexes as promising materials for the next generation of energy-saving OLED devices

LP Ravaro, KPS Zanoni, ASS de Camargo - Energy Reports, 2020 - Elsevier
The increasing demand for electrical energy by a longer living and increasing population
justifies the search for new, more efficient lighting systems. In this context, organo-metallic …

Copper dithiocarbamates: coordination chemistry and applications in materials science, biosciences and beyond

G Hogarth, DC Onwudiwe - Inorganics, 2021 - mdpi.com
Copper dithiocarbamate complexes have been known for ca. 120 years and find relevance
in biology and medicine, especially as anticancer agents and applications in materials …

Carbon disulfide. Just toxic or also bioregulatory and/or therapeutic?

AW DeMartino, DF Zigler, JM Fukuto… - Chemical Society …, 2017 - pubs.rsc.org
The overview presented here has the goal of examining whether carbon disulfide (CS2) may
play a role as an endogenously generated bioregulator and/or has therapeutic value. The …

Selective coordination of coinage metals using orthogonal ligand scaffolds

VR Naina, F Krätschmer, PW Roesky - Chemical Communications, 2022 - pubs.rsc.org
Group 11 metal complexes with their ability to form metallophilic interations are widely
pursued to develop multifunctional luminescent materials. Heteronuclear coinage metal …

Four octamolybdate complexes constructed from a quinoline–imidazole–monoamide ligand: structures and electrochemical, photocatalytic and magnetic properties

L Li, X Wang, N Xu, Z Chang, G Liu, H Lin, X Wang - CrystEngComm, 2020 - pubs.rsc.org
By introducing a quinoline–imidazole–monoamide ligand, N-(quinoline-5-yl)-1H-imidazole-
4-carboxamide (L), into reaction systems containing a [Mo7O24] 6− polyoxoanion and …

Bi-and trinuclear coinage metal complexes of a PNNP ligand featuring metallophilic interactions and an unusual charge separation

M Dahlen, M Kehry, S Lebedkin, MM Kappes… - Dalton …, 2021 - pubs.rsc.org
A selective synthesis of bi-and trinuclear complexes featuring a tetradentate monoanionic
PNNP ligand is presented. The binuclear coinage metal complexes show a typical fourfold …

Controlling the Size of Molecular Copper Clusters Supported by a Multinucleating Macrocycle

Q Wang, RP Murphy, MR Gau, PJ Carroll… - Inorganic …, 2024 - ACS Publications
The use of a nonrigid, pyridyldialdimine-derived macrocyclic ligand (3PDAI2) enabled the
synthesis of well-defined mono-, di-, tri-, and tetra-nuclear Cu (I) complexes in good yields …

New copper (i) complexes of bulky 5-substituted-2-iminopyrrolyl ligands as catalysts for azide–alkyne cycloaddition

TFC Cruz, PS Lopes, MANDA Lemos, LF Veiros… - Dalton …, 2023 - pubs.rsc.org
Five dinuclear copper (I) complexes of the type [Cu {κN, κN′-5-R-NC4H2-2-C (H) N (2, 6-
iPr2C6H3)}] 2 (1a–e; R= 2, 4, 6-iPr3C6H2 (a), R= 2, 6-Me2C6H3 (b), R= 3, 5-(CF3) 2C6H3 …

Synthesis, Characterization, and Reactivity of the Group 11 Hydrido Clusters [Ag6H4(dppm)4(OAc)2] and [Cu3H(dppm)3(OAc)2]

AW Cook, TAD Nguyen, WR Buratto, G Wu… - Inorganic …, 2016 - ACS Publications
The group 11 hydride clusters [Ag6H4 (dppm) 4 (OAc) 2](1) and [Cu3H (dppm) 3 (OAc)
2](2)(dppm= 1, 1-bis (diphenylphosphino) methane) were synthesized in moderate yields …