Direct Functionalization of para‐Quinones: A Historical Review and New Perspectives

R Kumar Jha, S Kumar - European Journal of Organic …, 2024 - Wiley Online Library
The direct functionalization of quinones has always fascinated research communities due to
their biological and redox activities and subsequent application. Quinone motifs play a vital …

Recent Development of Photoinduced Iron-Catalysis in Organic Synthesis

D Qian, W Taimin, F Lijing, Z Hongbin… - Chinese Journal of …, 2023 - sioc-journal.cn
In recent years, the development and application of transition metal ruthenium or iridium
complexes based photocatalysts have opened up a new research field for organic synthesis …

Blue Light Irradiated Metal-, Oxidant-, and Base-Free Cross-Dehydrogenative Coupling of C(sp2)–H and N–H Bonds: Amination of Naphthoquinones with Amines

RK Jha, M Batabyal, S Kumar - The Journal of Organic Chemistry, 2023 - ACS Publications
Herein, we report a blue-light-driven amination of C (sp 2)–H bond of naphthoquinones and
quinones with the N–H bond of primary and secondary amines for the synthesis of 2-amino …

Halogen Regulation in Vinylene-Linked Covalent Organic Frameworks for Efficient Photocatalytic C–H Thiolation of Quinone Derivatives

K Zhao, H Qiao, S Wang, X Xu, C Wang… - ACS Materials …, 2023 - ACS Publications
Vinylene-linked covalent organic frameworks (COFs) are considered promising
heterogeneous photocatalyst candidates for organic synthesis because of their robust and …

Electrochemical N-acylation and N-α-ketoacylation of sulfoximines via the selective decarboxylation and dehydration of α-ketoacids

C Kang, M Li, W Huang, S Wang, M Peng, L Zhao… - Green …, 2023 - pubs.rsc.org
Sulfoximines are commonly found in pharmaceuticals, agrochemicals and other biologically
active compounds. However, limited reports exist for their selective functionalization via …

Visible light/copper catalysis enabled Heck-like coupling between alkenes and cyclic sulfonium salts via selective C–S bond cleavage

X Liu, X Li, L Wang, Y Shi, J Lv, D Yang - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Developing new alkyl electrophiles for the construction of Csp3–Csp2 bonds through a Heck-
like coupling is a huge challenge and has attracted great interest in synthetic and medicinal …

Benzylamine promoted direct C–H arylation of arenes and heteroarenes via excitation with heat or light

S Chatterjee, S Azmi, N Bandopadhyay… - Organic & …, 2024 - pubs.rsc.org
Carbon–halogen bond cleavage in aryl halides through single electron transfer (SET) is a
crucial step in radical-based cross-coupling reactions. Accomplishing such cleavage using …

2, 3-Difunctionalization of quinones: a gold-catalyzed cascade approach for trifluoromethyl-amination or sulfoximination

A Sharma, V Govande, S Mahajan… - Chemical …, 2024 - pubs.rsc.org
A one-pot domino protocol employing gold (I) catalysis has been developed for the cascade
trifluoromethyl-amination/sulfoximination of quinones. Togni I serves as the trifluoromethyl …

Green Approach for N− H Functionalization of Sulfoximines: An Access to Sulfoximinated‐Oxime Conjugates

H Kour, A Sharma, J Kour, M Ahmed… - European Journal of …, 2022 - Wiley Online Library
A simple, metal‐free, and green approach has been established for N− H functionalization of
sulfoximines under mild reaction conditions to offer sulfoximinated‐oxime conjugates. The …

光诱导铁催化在有机合成中的应用研究进展

窦谦, 汪太民, 房丽晶, 翟宏斌, 程斌 - 有机化学, 2023 - sioc-journal.cn
摘要近年来, 以过渡金属钌和铱络合物为代表的光催化剂的开发和应用为有机合成开启了新篇章
, 这些过渡金属光催化剂参与的光催化反应为化学键的构筑和有机转化提供了温和高效的新策略 …