Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …

This review focuses on providing comprehensive highlights of the recent advances in the
field of cobalt-catalysed C–H functionalization and related synthetic concepts, relying on …

Sustainable transformations towards the production of valuable chemicals constantly attract
interest, both in terms of academic and applied research. C–H activation has long been …

Coordination bondings have shown their critical roles in various inorganic reactions after
Alfred Werner; however, it remains challenging to find extremely weak coordination bonding …

The ability of carboxylate groups to promote the direct functionalization of C–H bonds in
organic compounds is unquestionably one of the most important discoveries in modern …

The selective reactivity of carbamate and thiocarbamate toward alkylation and amidation is
reported under stable, high-valent, cost-effective cobalt (III) catalysis. This method reveals …

An efficient protocol for the synthesis of biologically essential pyrroloquinolinones has been
developed under Cp* CoIII catalysis, which involves a cascade reaction of C (7)–H …

Migratory insertion (MI) is one of the most important processes underpinning the transition
metal-catalysed formation of C–C and C–X bonds. In this work, a comprehensive model of …

Five-and six-coordinate cationic bis (phosphine) cobalt (III) metallacycle complexes were
synthesized with the general structures,[(depe) Co (cycloneophyl)(L)(L′)][BArF4](depe= 1 …

Co (III)-catalysed site-selective C8-allylation and vinylation of isoquinolones with allyl
acetate and vinyl acetates has been accomplished. The oxo group of isoquinolone has been …