The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

Reactions that enable carbon–nitrogen, carbon–oxygen and carbon–carbon bond formation
lie at the heart of synthetic chemistry. However, substrate prefunctionalization is often …

Covalent organic frameworks (COFs) are structurally tuneable, porous and crystalline
polymers constructed through the covalent attachment of small organic building blocks as …

Ultrathin polymeric carbon nitride nanosheets (PCN-NSs) are considered as a promising
semiconductor photocatalyst for CO 2 reduction, but the achieved efficiency is still …

Despite the fact that nucleophilic displacement (SN2) of alkyl halides with nitrogen
nucleophiles is one of the first reactions introduced in organic chemistry teaching, its …

Visible light‐mediated direct decarboxylation of carboxylic acids with an acridine
photocatalyst is a convenient and powerful method to generate carbon‐centered radicals in …

We report a photoinduced iron/copper dual-catalytic strategy for the radical decarboxylation
functionalization of aliphatic carboxylic acids. The photoinduced ligand-to-iron charge …

A visible-light photoredox-catalyzed method is reported that enables the coupling between
benzylic C–H substrates and N–H azoles. Classically, medicinally relevant N-benzyl azoles …

The reactivity of the sulfonyl group varies dramatically from nucleophilic sulfinates through
chemically robust sulfones to electrophilic sulfonyl halides—a feature that has been used …