Dithiocarbamate complexes as single source precursors to nanoscale binary, ternary and quaternary metal sulfides

JC Sarker, G Hogarth - Chemical Reviews, 2021 - ACS Publications
Nanodimensional metal sulfides are a developing class of low-cost materials with potential
applications in areas as wide-ranging as energy storage, electrocatalysis, and imaging. An …

Copper dithiocarbamates: coordination chemistry and applications in materials science, biosciences and beyond

G Hogarth, DC Onwudiwe - Inorganics, 2021 - mdpi.com
Copper dithiocarbamate complexes have been known for ca. 120 years and find relevance
in biology and medicine, especially as anticancer agents and applications in materials …

Ag (I) symmetrical N, N′-diarylformamidine dithiocarbamate PPh3 complexes: Synthesis, structural characterization, quantum chemical calculations and in vitro …

SD Oladipo, GF Tolufashe, C Mocktar, B Omondi - Inorganica Chimica Acta, 2021 - Elsevier
Three heteroleptic silver (I) dithiocarbamate triphenylphosphine complexes were developed
in which triphenylphosphine was introduced as a bulky co-ligand and tested as antioxidant …

The supramolecular frameworks and electrocatalytic properties of two new structurally diverse tertiary phosphane-appended nickel (ii) and copper (i) thiosquarates

D Srivastava, A Kushwaha, G Kociok-Köhn… - …, 2023 - pubs.rsc.org
In this study, two new heteroleptic complexes with compositions [Ni (mtsq) 1.85 Cl0. 15
(dppe)](CH2Cl2) 0.06 (CH3OH) 0.09 (Ni-mtsq) and [Cu (mtsq)(PPh3) 2](Cu-mtsq)(dppe= 1 …

[HTML][HTML] In vitro biological studies of heteroleptic Ag (I) and Cu (I) unsymmetrical N, N′-diarylformamidine dithiocarbamate phosphine complexes; the effect of the …

SD Oladipo, C Mocktar, B Omondi - Arabian Journal of Chemistry, 2020 - Elsevier
A series of five dithiocarbamate and their respective Ag (I) and Cu (I) triphenylphosphine
complexes of the general formula [Ag/Cu (PPh 3) 2 L] were synthesized and characterized …

Pseudo-Tetrahedral Copper (I) Symmetrical Formamidine Dithiocarbamate-Phosphine Complexes: Antibacterial, Antioxidant and Pharmacokinetics Studies

SD Oladipo, B Omondi - Inorganics, 2022 - mdpi.com
Three copper (I) dithiocarbamate–phosphine complexes of the general formula Cu (PPh3)
2L were synthesized by metathesis reactions of the potassium salt of the dithiocarbamate …

Copper (I) tertiary phosphine xanthate complexes as single source precursors for copper sulfide and their application in the OER

A Singh, M Trivedi, P Singh, G Kociok-Köhn… - New Journal of …, 2018 - pubs.rsc.org
Three isomeric bis-(triphenylphosphine) copper (I) complexes comprising xanthate ligands
derived from 2-(1), 3-(2), and 4-methanol pyridine (3) have been synthesized and …

On the coordination role of pyridyl-nitrogen in the structural chemistry of pyridyl-substituted dithiocarbamate ligands

ERT Tiekink - Crystals, 2021 - mdpi.com
A search of the Cambridge Structural Database was conducted for pyridyl-substituted
dithiocarbamate ligands. This entailed molecules containing both an NCS2− residue and …

Highly efficient and recyclable pre-catalysts based on mono-and dinuclear heteroleptic Cu (I) dithio-PPh3 complexes to produce variety of glycoconjugate triazoles

AK Singh, CL Yadav, KB Mishra, SK Singh, AN Gupta… - Molecular catalysis, 2019 - Elsevier
Highly efficient and reusable pre-formed mono-and dinuclear heteroleptic copper (I)
dithiocarbamate and dithiocarbimate complex based catalysts,[Cu (PPh 3) 2 (L)] and [Cu 2 …

Antioxidant potential and secondary reactivity of bisdiphenyl(2-pyridyl)phosphinocopper(II) complex

E Khan, A Shahzad, MN Tahir… - Turkish Journal of …, 2018 - journals.tubitak.gov.tr
Copper-based complexes with the general formulas [Cu (L) $ _ {2} $] Cl $ _ {2} $(1) and [Cu
$ _ {2} $ L $ _ {2} $($\mu_ {2} $-L) $\mu_ {2-} $ Cl $ _ {2} $](2) and a mixed-ligand anionic …