Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

High-entropy nanoparticles: Synthesis-structure-property relationships and data-driven discovery

Y Yao, Q Dong, A Brozena, J Luo, J Miao, M Chi… - Science, 2022 - science.org
High-entropy nanoparticles have become a rapidly growing area of research in recent years.
Because of their multielemental compositions and unique high-entropy mixing states (ie …

Single-atom (iron-based) catalysts: synthesis and applications

B Singh, MB Gawande, AD Kute, RS Varma… - Chemical …, 2021 - ACS Publications
Supported single-metal atom catalysts (SACs) are constituted of isolated active metal
centers, which are heterogenized on inert supports such as graphene, porous carbon, and …

Lattice‐Strain Engineering for Heterogenous Electrocatalytic Oxygen Evolution Reaction

Z Hou, C Cui, Y Li, Y Gao, D Zhu, Y Gu… - Advanced …, 2023 - Wiley Online Library
The energy efficiency of metal–air batteries and water‐splitting techniques is severely
constrained by multiple electronic transfers in the heterogenous oxygen evolution reaction …

Progressive growth of the solid–electrolyte interphase towards the Si anode interior causes capacity fading

Y He, L Jiang, T Chen, Y Xu, H Jia, R Yi, D Xue… - Nature …, 2021 - nature.com
The solid–electrolyte interphase (SEI), a layer formed on the electrode surface, is essential
for electrochemical reactions in batteries and critically governs the battery stability. Active …

Machine learning in scanning transmission electron microscopy

SV Kalinin, C Ophus, PM Voyles, R Erni… - Nature Reviews …, 2022 - nature.com
Scanning transmission electron microscopy (STEM) has emerged as a uniquely powerful
tool for structural and functional imaging of materials on the atomic level. Driven by …

Determining the three-dimensional atomic structure of an amorphous solid

Y Yang, J Zhou, F Zhu, Y Yuan, DJ Chang, DS Kim… - Nature, 2021 - nature.com
Amorphous solids such as glass, plastics and amorphous thin films are ubiquitous in our
daily life and have broad applications ranging from telecommunications to electronics and …

Electron microscopy studies of soft nanomaterials

Z Lyu, L Yao, W Chen, FC Kalutantirige… - Chemical …, 2023 - ACS Publications
This review highlights recent efforts on applying electron microscopy (EM) to soft (including
biological) nanomaterials. We will show how developments of both the hardware and …

Vanadium as auxiliary for Fe–V dual-atom electrocatalyst in lithium–sulfur batteries:“3D in 2D” morphology inducer and coordination structure regulator

L Yang, Y Pan, Z Zhou, Y Zhang, J Xu, C Ma, Y Zhang… - ACS …, 2023 - ACS Publications
The undesirable shuttling behavior, the sluggish redox kinetics of liquid–solid
transformation, and the large energy barrier for decomposition of Li2S have been the …

Atomically precise control in the design of low-nuclearity supported metal catalysts

S Mitchell, J Pérez-Ramírez - Nature Reviews Materials, 2021 - nature.com
Nanostructured catalysts incorporating supported metal atoms or small clusters of defined
size and chemical composition attract considerable attention because of their potential to …