Recent years have witnessed an increase in the popularity of α-boryl organometallic
reagents as versatile nucleophiles in asymmetric synthesis. These compounds have been …

gem-Diborylalkanes are an important class of organoboron compounds as they function as
a key building block in organic synthesis. In the last decade, there has been growing interest …

Cyclopropane skeletons play a prominent role in the development of organic synthesis and
pharmaceutical chemistry. Herein, we report the design and synthesis of a stable …

Cu-catalyzed highly stereoselective and enantiodivergent syntheses of (Z)-or (E)-β, γ-
unsaturated ketones from 1, 3-butadienyl silanes are developed. The nature of the silyl …

While 1, 1-diboryl (gem-diboryl) compounds are valuable synthetic building blocks,
currently, related studies have mainly focused on those 1, 1-diboryl alkanes without a hetero …

We report herein a Cu‐catalyzed regio‐, diastereo‐and enantioselective acylboration of 1, 3‐
butadienylboronate with acyl fluorides. Under the developed conditions, the reactions …

The development of boron reagents is crucial for synthetic chemistry. Herein, we present a
scalable and practical synthesis of diborodichloromethane (DBDCM) through the reaction of …

General methods for the preparation of geminal bis (boronates) are of great interest due to
their widespread applications in organic synthesis. While the terminal gem‐diboron …

Polyborylated-alkenes are valuable polymetalloid reagents in modern organic synthesis,
providing access to a wide array of transformations, including the construction of multiple C …

Allylation and propargylation are two powerful synthetic strategies for making new
substances that have been of significant importance in chemistry, medicine, and material …