Palladium covalently anchored imidazolium functionalized SBA-15: An efficient recoverable heterogeneous catalyst for the hydrocarboxylation of styrene

Y Tao, M Ma, W Li, L Zhou, L Li, Z Guo, C Zhang… - Journal of Solid State …, 2024 - Elsevier
Abstract An efficient Pd/Imi-SBA-15 heterogeneous catalyst was synthesized by a covalent
anchoring strategy for the hydrocarboxylation of styrene. Various characterization methods …

The Critical Role of Ligand Flexibility on the Activity of Free and Immobilized Mn Superoxide Dismutase Mimics

M Richezzi, S Signorella, C Palopoli, N Pellegri… - Inorganics, 2023 - mdpi.com
In low-molecular-weight Mn superoxide dismutase (SOD) mimics, the ligand plays a key role
in tuning the reactivity of the metal center with O2•−. We used three ligands differing in their …

Effect of Metal Environment and Immobilization on the Catalytic Activity of a Cu Superoxide Dismutase Mimic

M Richezzi, J Ferreyra, S Signorella, C Palopoli… - Inorganics, 2023 - mdpi.com
The Cu (II)/Cu (I) conversion involves variation in the coordination number and geometry
around the metal center. Therefore, the flexibility/rigidity of the ligand plays a critical role in …

Cu (II) and Mn (II) Anchored on Functionalized Mesoporous Silica with Schiff Bases: Effects of Supports and Metal–Ligand Interactions on Catalytic Activity

M Mureseanu, M Filip, I Bleotu, CI Spinu, AH Marin… - Nanomaterials, 2023 - mdpi.com
New series of Cu (II) and Mn (II) complexes with Schiff base ligands derived from 2-
furylmethylketone (Met), 2-furaldehyde (Fur), and 2-hydroxyacetopheneone (Hyd) have …

[HTML][HTML] Cytotoxic ROS-Consuming Mn (III) Synzymes: Structural Influence on Their Mechanism of Action

L Verderi, N Nova, V Borghesani, M Tegoni… - International Journal of …, 2024 - mdpi.com
ROS (ie, reactive oxygen species) scavenging is a key function of various Mn-based
enzymes, including superoxide dismutases (SODs) and catalases, which are actively linked …