Investigation of f-Element Interactions with Functionalized Diamides of Phenanthroline-Based Ligands
Separations relevant to trivalent actinides and lanthanides have been a focus of the f-
element community in the past few decades. A central focus of this effort has been …
element community in the past few decades. A central focus of this effort has been …
Computational Tools and Techniques in Designing Ligands for the Selective Separation of Actinide and Lanthanide: A Review
C Ebenezer, RV Solomon - Comments on Inorganic Chemistry, 2024 - Taylor & Francis
The development of density functional theory (DFT) has significantly enhanced the use of
computational chemistry as a tool in the design and development of ligands for the …
computational chemistry as a tool in the design and development of ligands for the …
The effects of structural variations in neutral phosphorus extractants on UO22+ extraction behavior and radiation stability: experimental and theoretical insights
Q Guo, Y Chen, P Zhang, Y Liu, Y Li, Y Yang… - Journal of Molecular …, 2023 - Elsevier
In the present work, the effects of four neutral phosphorus extractants (TBP, TAP, THP,
TEHP) with different molecular structures on the extraction behaviors towards U (Ⅵ) and …
TEHP) with different molecular structures on the extraction behaviors towards U (Ⅵ) and …
Theoretical insights into the selectivity of hydrophilic sulfonated and phosphorylated ligands to Am (III) and Eu (III) ions
Y Zou, JH Lan, LY Yuan, CZ Wang, QY Wu… - Inorganic …, 2023 - ACS Publications
The separation of lanthanides and actinides has attracted great attention in spent nuclear
fuel reprocessing up to date. In addition, liquid–liquid extraction is a feasible and useful way …
fuel reprocessing up to date. In addition, liquid–liquid extraction is a feasible and useful way …
Selective complexation of trivalent americium over europium with substituted Triazolebipyridine-based ligand in high Level-Liquid Waste-A DFT Investigation
C Ebenezer, RV Solomon - Polyhedron, 2022 - Elsevier
Similar chemical properties like ionic radius and oxidation states exhibited by trivalent
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …
Preorganization of N, O-hybrid phosphine oxide chelators for effective extraction of trivalent Am/Eu ions–a computational study
C Ebenezer, RV Solomon - New Journal of Chemistry, 2022 - pubs.rsc.org
N, O-Hybrid phosphine oxide ligands with N-heterocyclic cores are advanced extractants for
extracting actinides over lanthanides. However, the challenging task in designing an …
extracting actinides over lanthanides. However, the challenging task in designing an …
Selective Recovery of Cerium as High-Purity Oxides via Reactive Separation Using CO2-Responsive Structured Ligands
Development of new ligand systems that selectively extract and release critical elements,
such as lanthanides, in the presence of other metal ions at significantly higher …
such as lanthanides, in the presence of other metal ions at significantly higher …
Theoretically investigating the ability of phenanthroline derivatives to separate transuranic elements and their bonding properties
Y Zhang, S Wu, A Li - New Journal of Chemistry, 2022 - pubs.rsc.org
With the development of green chemistry, it is necessary to extract minor actinides from toxic
high-level liquid waste. Hence, we need to explore the nature of bonding between ligands …
high-level liquid waste. Hence, we need to explore the nature of bonding between ligands …
[PDF][PDF] Selective complexation of trivalent americium over europium with substituted Triazolebipyridine-based ligand in high Level-Liquid Waste-A DFT Investigation
C Ebenezer, RV Solomon - Polyhedron, 2022 - drive.google.com
Similar chemical properties like ionic radius and oxidation states exhibited by trivalent
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …
Complexation of N‐Heterocyclic Substituted 1,10‐Phenanthroline‐2,9‐diamide with Am3+/Eu3+ Ions for Nuclear Waste Water Treatment
C Ebenezer, RV Solomon - ChemistrySelect, 2022 - Wiley Online Library
Designing organic ligands is a popular strategy in removing hazardous radioactive
substances from nuclear wastewater which has been a major environmental concern. In this …
substances from nuclear wastewater which has been a major environmental concern. In this …