A review on the chemistry of magnesium porphyrins, which have significant interest owing to
the relevance to chlorophyll molecules, is presented with emphasis on bicarbonate adducts …

This review provides a summary of reaction mechanisms involving the interactions of nitrite
ion with metal centers relevant to physiology. The majority of the systems that have been …

A new aerobic route is introduced for the oxidation of a variety of aromatic and aliphatic
aldehydes to the corresponding carboxylic acid derivatives using molecular oxygen in the …

In this work, a new aerobic route is introduced for the selective oxidation of a variety of
aromatic and aliphatic alcohols to the corresponding aldehyde and ketone derivatives by …

The crystal structure of 5, 10, 15, 20-tetra (ethoxycarbonyl) porphyrin copper (II) showed that
its central copper has a six-coordinate structure. An efficient copper porphyrin-catalyzed …

Metal-halides that perform proton coupled electron-transfer (PCET) oxidation are an
important new class of high-valent oxidant. In investigating metal-dihalides, we reacted [FeIII …

Iron (III) isoporphyrin, a tautomer of porphyrin with a saturated meso carbon, is one of the
isoelectronic forms of oxoiron (IV) porphyrin π-cation radical, which is known as an important …

Accumulating evidence suggests that abnormal levels of homocysteine are associated with
vascular dysfunctions, cancer cell proliferation and various neurodegenerative diseases …

The selective oxidation of the α-position of two heme-FeIII tetraarylporphryinate complexes
occurs when water (hydroxide) attacks their oxidized Cmpd I-type equivalents, high-valent …

Cytochrome c oxidase (C c O) catalyzes the reduction of dioxygen to water utilizing a
heterobinuclear active site composed of a heme moiety and a mononuclear copper center …