The golden age of thermally activated delayed fluorescence materials: design and exploitation

JM Dos Santos, D Hall, B Basumatary… - Chemical …, 2024 - ACS Publications
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …

Two-coordinate thermally activated delayed fluorescence coinage metal complexes: Molecular design, photophysical characters, and device application

TY Li, SJ Zheng, PI Djurovich, ME Thompson - Chemical Reviews, 2024 - ACS Publications
Since the emergence of the first green light emission from a fluorescent thin-film organic light
emitting diode (OLED) in the mid-1980s, a global consumer market for OLED displays has …

Intersystem crossing, phosphorescence, and spin-orbit coupling. Two contrasting Cu (I)-TADF dimers investigated by milli-to micro-second phosphorescence, femto …

H Yersin, R Czerwieniec, U Monkowius… - Coordination Chemistry …, 2023 - Elsevier
Applying femto-second time-resolved spectroscopy, we study intersystem crossing times τ
(ISC) of two Cu (I) dimers, Cu 2 Cl 2 (dppb) 2 1 (dppb= 1, 2-bis-diphenylphosphino) …

Thermally Activated Delayed Fluorescence (TADF) Materials Based on Earth‐Abundant Transition Metal Complexes: Synthesis, Design and Applications

V Ferraro, C Bizzarri, S Bräse - Advanced Science, 2024 - Wiley Online Library
Materials exhibiting thermally activated delayed fluorescence (TADF) based on transition
metal complexes are currently gathering significant attention due to their technological …

The trade-off anionic modulation in metal–organic glasses showing color-tunable persistent luminescence

T Chen, YJ Ma, G Xiao, X Fang, Y Liu, K Li, D Yan - Materials Horizons, 2024 - pubs.rsc.org
Ultralong room-temperature phosphorescence (RTP) and thermally activated delayed
fluorescence (TADF) materials provide exciting opportunities for the rational design of …

Understanding and designing thermally activated delayed fluorescence emitters: beyond the energy gap approximation

J Eng, TJ Penfold - The Chemical Record, 2020 - Wiley Online Library
In this article recent progress in the development of molecules exhibiting Thermally
Activated Delayed Fluorescence (TADF) is discussed with a particular focus upon their …

Multistimuli-responsive behavior of a phosphorescent Cu 3 pyrazolate 3 complex for luminescent logic gates and encrypted information transformation

WJ Tang, H Yang, SK Peng, ZM Xiao… - Inorganic Chemistry …, 2023 - pubs.rsc.org
Multistimuli-responsive luminescent materials, showing obvious alteration of emission
colours or intensity toward multiple external stimuli, have attracted extensive interest from …

Crystalline metal‐organic materials with thermally activated delayed fluorescence

Z Han, XY Dong, SQ Zang - Advanced Optical Materials, 2021 - Wiley Online Library
Thermally activated delayed fluorescence (TADF) properties of crystalline metal‐organic
materials, mainly including small‐molecule metal–organic complexes, organic ligand …

Silver (I)–Organic Frameworks Showing Remarkable Thermo-, Solvato-And Vapochromic Phosphorescence As Well As Reversible Solvent-Driven 3D-to-0D …

MI Rogovoy, AS Berezin, DG Samsonenko… - Inorganic …, 2021 - ACS Publications
A series of isoreticular Ag (I) luminescent metal–organic frameworks (LMOFs),{[Ag2L2
(CH3CN) 2](X) 2} n (X= ClO4, OTf, and BF4), has been designed, exploiting diphenyl (2 …

Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

AV Paderina, IO Koshevoy, EV Grachova - Dalton Transactions, 2021 - pubs.rsc.org
Copper subgroup metal ions in the+ 1 oxidation state are classical candidates for
aggregation via non-covalent metal–metal interactions, which are supported by a number of …