Molecular characterization of polymer networks

SPO Danielsen, HK Beech, S Wang… - Chemical …, 2021 - ACS Publications
Polymer networks are complex systems consisting of molecular components. Whereas the
properties of the individual components are typically well understood by most chemists …

Designing complex fluids

RH Ewoldt, C Saengow - Annual Review of Fluid Mechanics, 2022 - annualreviews.org
Taking a small step away from Newtonian fluid behavior creates an explosion in the range of
possibilities. Non-Newtonian fluid properties can achieve diverse flow objectives, but the …

Dissipation and strain-stiffening behavior of pectin–Ca gels under LAOS

J John, D Ray, VK Aswal, AP Deshpande, S Varughese - Soft Matter, 2019 - pubs.rsc.org
Non-linear mechanical responses observed in networks of many biopolymers such as pectin
are important for their functioning as biological systems. Additionally, pectins derived from …

Rheology and pinching dynamics of associative polysaccharide solutions

CDV Martínez Narváez, J Dinic, X Lu, C Wang… - …, 2021 - ACS Publications
Associative polysaccharides, decorated by multiple but short, side-chain hydrophobic
stickers (typically 6–20 carbon long) that associate in solution, are used as thickeners for an …

Shear Thickening Behavior in Injectable Tetra-PEG Hydrogels Cross-Linked via Dynamic Thia-Michael Addition Bonds

AD Crowell, TM FitzSimons, EV Anslyn… - …, 2023 - ACS Publications
Injectable poly (ethylene glycol)(PEG)-based hydrogels were reversibly cross-linked through
thia-conjugate addition bonds and demonstrated to shear thicken at low shear rates. Cross …

Linear viscoelasticity of associative polymers: Sticky Rouse model and the role of bridges

N Jiang, H Zhang, P Tang, Y Yang - Macromolecules, 2020 - ACS Publications
Polymers bearing associative groups can exhibit fascinating rheological behaviors. A
modified version of the Rouse model, which is originally used in block copolymers and …

Elongational Rheology of Entangled Ionomers Based on Poly (hexyl methacrylate)

S Wu, H Yang, Z Zhang, Q Chen - Macromolecules, 2023 - ACS Publications
Linear viscoelasticity (LVE) and nonlinear elongational behavior are examined for a series
of entangled ionomers based on poly (hexyl methacrylate) as the backbone and sodium …

Anisotropic Liesegang pattern for the nonlinear elastic biomineral-hydrogel complex

W Choi, M Lee, H Yong, D Heo, T Jun, H Ryu… - Science …, 2024 - science.org
The Liesegang pattern is a beautiful natural anisotropic patterning phenomenon observed in
rocks and sandstones. This study reveals that the Liesegang pattern can induce nonlinear …

Influences of chemical crosslinking, physical associating, and filler filling on nonlinear rheological responses of polyisoprene

X Fan, H Xu, C Wu, Y Song, Q Zheng - Journal of Rheology, 2020 - pubs.aip.org
Chemical crosslinking, physical associating, and filler filling play vital roles in nonlinear
responses of rubbers under large amplitude oscillatory shear (LAOS). Herein, a systematical …

Modulating noncovalent cross-links with molecular switches

ES Epstein, L Martinetti, RH Kollarigowda… - Journal of the …, 2019 - ACS Publications
Spiropyran molecular switches, in conjunction with transition metal ions, are shown to
operate as reversible polymer cross-linkers. Solutions containing a spiropyran …