Carbohydrate-based macromolecular biomaterials

L Su, Y Feng, K Wei, X Xu, R Liu, G Chen - Chemical Reviews, 2021 - ACS Publications
Carbohydrates are the most abundant and one of the most important biomacromolecules in
Nature. Except for energy-related compounds, carbohydrates can be roughly divided into …

Beyond nylon 6: Polyamides via ring opening polymerization of designer lactam monomers for biomedical applications

M Varghese, MW Grinstaff - Chemical Society Reviews, 2022 - pubs.rsc.org
Ring opening polymerization (ROP) of lactams is a highly efficient and versatile method to
synthesize polyamides. Within the last ten years, significant advances in polymerization …

Controlled Living Cascade Polymerization To Make Fully Degradable Sugar-Based Polymers from d-Glucose and d-Galactose

A Bhaumik, GI Peterson, C Kang… - Journal of the American …, 2019 - ACS Publications
Monomers derived from glucose and galactose, which contain an endocyclic alkene (in the
sugar ring) and a terminal alkyne, underwent a cascade polymerization to prepare new …

Synthesis of bioactive (1→ 6)-β-glucose branched poly-amido-saccharides that stimulate and induce M1 polarization in macrophages

R Xiao, J Zeng, EM Bressler, W Lu… - Nature …, 2022 - nature.com
Abstract β-Glucans are of significant interest due to their potent antitumor and
immunomodulatory activities. Nevertheless, the difficulty in purification, structural …

Invoking Side-Chain Functionality for the Mediation of Regioselectivity during Ring-Opening Polymerization of Glucose Carbonates

Y Song, X Yang, Y Shen, M Dong, YN Lin… - Journal of the …, 2020 - ACS Publications
The extent of participation of side-chain functionalities during the 1, 5, 7-triazabicyclo [5.4. 0]
dec-5-ene (TBD) organobase-catalyzed ring-opening polymerizations (ROP) of six …

Advancing the development of highly-functionalizable glucose-based polycarbonates by tuning of the glass transition temperature

Y Song, X Ji, M Dong, R Li, YN Lin… - Journal of the …, 2018 - ACS Publications
Fundamental studies that gain an understanding of the tunability of physical properties of
natural product-based polymers are vital for optimizing their performance in extensive …

Polymers from sugars and unsaturated fatty acids: ADMET polymerisation of monomers derived from D-xylose, D-mannose and castor oil

M Piccini, DJ Leak, CJ Chuck, A Buchard - Polymer Chemistry, 2020 - pubs.rsc.org
α, ω-Unsaturated glycolipids derived from natural monosaccharides D-xylose and D-
mannose, and from a castor oil derivative, 10-undecenoic acid, were synthesised and …

Chemistry-driven glycoscience

LL Kiessling - Bioorganic & Medicinal Chemistry, 2018 - Elsevier
Carbohydrates are the most prominent features of the cell's exterior—they are the cell's
“face” and serve as the cell's identification card. The features of cell surface glycans (eg …

Analysis of carbohydrates and glycoconjugates by matrix‐assisted laser desorption/ionization mass spectrometry: An update for 2017–2018

DJ Harvey - Mass Spectrometry Reviews, 2023 - Wiley Online Library
This review is the tenth update of the original article published in 1999 on the application of
matrix‐assisted laser desorption/ionization mass spectrometry (MALDI) mass spectrometry …

In Situ Generation of Magnesium‐and Calcium‐Based Grignard Reagents for Amide Synthesis

P Schüler, S Sengupta, S Krieck… - … –A European Journal, 2023 - Wiley Online Library
The alkaline‐earth metals Mg and Ca are too inert for the direct metalation of primary and
secondary amines. Consequently, activation prior to use is required. Alternatively, the …