Topochemical Polymerization at Diacetylene Metal–Organic Framework Thin Films for Tuning Nonlinear Optics

ZB Jin, G Zhou, Y Han, Z Huang, ZG Gu… - Journal of the American …, 2024 - ACS Publications
Developing the topochemical polymerization of metal–organic frameworks (MOFs) is of
pronounced significance for expanding their functionalities but is still a challenge on third …

Soluble and processable single-crystalline cationic polymers

Y Liu, XR Guan, DC Wang, JF Stoddart… - Journal of the American …, 2023 - ACS Publications
Single-crystal-to-single-crystal (SCSC) polymerization offers an effective protocol for the
environmentally friendly preparation of polymer single crystals (PSCs) with extremely high …

Modular programming of hierarchy and diversity in multivariate polymer/metal–organic framework hybrid composites

L Feng, XL Lv, TH Yan, HC Zhou - Journal of the American …, 2019 - ACS Publications
The idea that complex systems have a hierarchical arrangement has been widely observed
on various scales. In this work, we introduce the concept of modular programming, which …

Designed Synthesis of a 1D Polymer in Twist‐Stacked Topology via Single‐Crystal‐to‐Single‐Crystal Polymerization

V Athiyarath, KM Sureshan - Angewandte Chemie, 2020 - Wiley Online Library
To synthesize a fully organic 1D polymer in a novel twist‐stacked topology, we designed a
peptide monomer HC≡ CCH2‐NH‐Ile‐Leu‐N3, which crystallizes with its molecules H …

Construction of unprecedented pillar-layered metal organic frameworks via a dual-ligand strategy for dye degradation

YH Tang, F Wang, J Zhang - Dalton Transactions, 2018 - pubs.rsc.org
A dual-ligand strategy is used to construct two pillar-layered metal organic frameworks
(MOFs) with [Zn2 (COO) 3]+ subunits (SBUs) and [ZnxCo3− x (ethanol) 2 (COO) 4] 2+ SBUs …

Living metathesis and metallotropy polymerization gives conjugated polyenynes from multialkynes: how to design sequence-specific cascades for polymers

C Kang, S Kwon, JC Sung, J Kim… - Journal of the …, 2018 - ACS Publications
On the basis of a combined experimental and computational study, a novel method for
preparing fully conjugated polyenynes via cascade metathesis and metallotropy (M&M) …

Stereoselective Solid-State Synthesis of Biologically Active Cyclobutane and Dicyclobutane Isomers via Conformation Blocking and Transference

Z Qin, Y Gu, D Young, F Hu, Z Luo - Molecules, 2024 - mdpi.com
Conformations in the solid state are typically fixed during crystallization. Transference of
“frozen” C= C conformations in 3, 5-bis ((E)-2-(pyridin-4-yl) vinyl) methylbenzene (CH3-3, 5 …

Rational Design of Diphenyldiacetylene‐Based Fluorescent Materials Enabling a 365‐nm Light‐Initiated Topochemical Polymerization

M Zhu, L Zhu - Chemistry–An Asian Journal, 2021 - Wiley Online Library
Photopolymerization of diacetylenes usually requires stringent reaction conditions like high
energy irradiation of 254‐nm light or even γ‐rays, which are generally harmful to the human …

[引用][C] Engineering Heterarchy and Hierarchy in Metal-Organic Frameworks

L Feng - 2020