Theoretical Chemistry of Gold - Pyykkö - 2004 - Angewandte Chemie International Edition - Wiley
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Gas‐phase experiments provide information which, in conjunction with results from
electronic structure calculations, help to unravel the critical role relativistic effects play in …

Abstract Die besonderen Eigenschaften des Golds sind entscheidend durch relativistische
Effekte bestimmt. Mittlerweile existiert eine Vielzahl zuverlässiger Rechnungen zu …

Electron affinity (EA), defined as the amount of energy necessary to remove an electron from
an anion, plays a dominant role in reactivity. This is evidenced by halogen atoms, whose …

We report the discovery of a new class of magnetic superhalogens and their unusually
stable (magic) molecular anions. These are formed when a hot plume of manganese atoms …

Über den Nachweis der Existenz schwer fassbarer Moleküle hinaus dienen
Gasphasenexperimente, in Verbindung mit Ergebnissen aus quantenchemischen …

Gold is the classic noble metal as shown by its use for valued ornaments through the ages.
Gold does not oxidize nor adsorb most molecules from the gas phase.[1] However …

The mononuclear gold (II) halide complexes [AuCl3]− and [AuBr3]− are formed in the gas
phase by collision‐induced homolytic splitting of the only Au− C bond in the monoalkylgold …

In recent years, many experimental and theoretical studies have been devoted to the
determination of the properties of small metal-containing molecules in the gas phase. Much …

[(P4) 2Ag]+.[4a] The nature of the bonding in these cations, especially in the P4 [4b] and in
the related CO [5] complexes, has been of the subject of recent controversies. The LUMOs …