Investigating hollandite–perovskite composite ceramics as a potential waste form for immobilization of radioactive cesium and strontium

J Ma, Z Fang, X Yang, B Wang, F Luo, X Zhao… - Journal of Materials …, 2021 - Springer
Ceramic matrix containing zirconolite, hollandite, and perovskite phases is proposed as a
potential host for HLW immobilization. Hollandite phase principally immobilizes Cs, while …

Hollandites' crystal chemistry, properties, and processing: A review

P Tumurugoti, S Betal, SK Sundaram - International Materials …, 2021 - Taylor & Francis
This review provides a broad overview of the structural characteristics, compositional
flexibility, and structure–property relationships of hollandite materials. Hollandites have a …

Compositional control of tunnel features in hollandite-based ceramics: structure and stability of (Ba,Cs)1.33(Zn,Ti)8O16

R Grote, M Zhao, L Shuller-Nickles, J Amoroso… - Journal of materials …, 2019 - Springer
The impact of composition on the tunnel features of hollandite materials for the purpose of
radioactive cesium (Cs) immobilization was evaluated. The barium (Ba) to cesium (Cs) ratio …

Structural stability and aqueous durability of Cs incorporation into BaAl2Ti6O16 hollandite

Z Fang, X Xu, X Yang, H Xie, X Zhao, B Wang… - Journal of Nuclear …, 2022 - Elsevier
Hollandite ceramics are well-recognized as a promising host for immobilizing radioactive
cesium. In the present paper, the [Ba x Cs y][(Al 3+, Ti 3+) 2 x+ y Ti 4+ 8-2 xy] O 16 (0.4≤ x …

Enhanced crevice corrosion of stainless steel 316 by degradation of Cr-containing hollandite crevice former

X Guo, P Lei, C Mohanty, T Yao, J Lian, GS Frankel - Corrosion Science, 2022 - Elsevier
This study explores the corrosion interactions between stainless steel 316 (SS316), a
candidate nuclear waste canister material, and Cr-containing hollandite (Ba 1.15 Cr 2.3 Ti …

Low temperature fabrication of Ba0. 9Cs0. 3Cr2. 1Ti5. 9O16 ceramic waste form for cesium immobilization using Bi2O3 as sintering aid

X Xu, X Ning, F Dong, X Yang, W Zhang, B Ye… - Chemical Engineering …, 2024 - Elsevier
In this paper, we present a productive low-temperature fabrication of Cs-hollandite ceramics
by adding Bi 2 O 3 as a sintering aid to achieve high cesium retention. The effects of Bi 2 O 3 …

Structural Evolution in Hollandite Solid Solutions Across the A‐Site Compositional Range from Ba1.33Ga2.66Ti5.34O16 to Cs1.33Ga1.33Ti6.67O16

Y Xu, M Feygenson, K Page, LS Nickles… - Journal of the …, 2016 - Wiley Online Library
Hollandite solid solutions along the A‐site compositional range from the pure barium end‐
member Ba1. 33Ga2. 66Ti5. 34O16 to the pure cesium end‐member Cs1. 33Ga1. 33Ti6 …

[HTML][HTML] Atomistic scale investigation of cation ordering and phase stability in Cs-substituted Ba1. 33Zn1. 33Ti6. 67O16, Ba1. 33Ga2. 66Ti5. 67O16 and Ba1. 33Al2 …

Y Wen, Y Xu, KS Brinkman, L Shuller-Nickles - Scientific reports, 2018 - nature.com
The titanate-based hollandite structure is proposed as an effective ceramic waste form for Cs-
immobilization. In this study, quantum-mechanical calculations were used to quantify the …

A Potential Wasteform for Cs Immobilization: Synthesis, Structure Determination, and Aqueous Durability of Cs2TiNb6O18

TY Chen, ER Maddrell, NC Hyatt, JA Hriljac - Inorganic Chemistry, 2016 - ACS Publications
Cs2TiNb6O18 is a potential ceramic wasteform for the long-term immobilization of
radioactive cesium. Cs2TiNb6O18 was synthesized using the aqueous precursor method …

Radiation tolerant ceramics for nuclear waste immobilization: Structure and stability of cesium containing hollandite of the form (Ba, Cs) 1.33 (Zn, Ti) 8O16 and (Ba, Cs …

R Grote, T Hong, L Shuller-Nickles, J Amoroso… - Journal of Nuclear …, 2019 - Elsevier
The radiation damage tolerance of nuclear waste forms is dependent on the material's
resistance to defect formation and its ability to accommodate structural distortions that arise …