Synthetic chemists have long focused on selective C (sp 3)–N bond-forming approaches in
response to the high value of this motif in natural products, pharmaceutical agents and …

The use of visible light to promote synthetic processes has been emerging rapidly in recent
years. In the frame of eco-sustainable strategies involving the generation of reactive …

Alkylboronic pinacol esters (APEs) are highly versatile reagents in organic synthesis.
However, the direct generation of alkyl radicals from commonly used, bench-stable APEs …

Nitroso compounds have emerged as highly valuable reaction partners or reagents in
organic synthesis due to their rich reactivity. The versatile profile of these compounds allows …

We developed a photoinduced method for vicinal sulfamoyloximation of alkenes using N-
nitrosamines as bifunctional reagents, with DABSO serving as both a sulfonyl source and a …

N-Nitrosamines represent a class of bifunctional nitrogen-radical precursors, but their
application potential remains largely unexplored. This study reports the highly atom …

In recent decades, the traceless nature of visible photons has been exploited for the
development of efficient synthetic strategies for the photoconversion of colourless …

A convenient and practical hydrosulfonylation and disulfonylation of substituted maleimides
was realized using sulfonyl hydrazides as the sulfur reagent and tert-butyl hydroperoxide as …

Dearomative spirocyclization reactions represent a promising means to convert arenes into
three‐dimensional architectures; however, controlling the regioselectivity of radical …

An efficient Barton nitrite ester-type cyclization reaction of N-ethyl-N-nitrosobenzamides to
synthesize benzo [d][1, 2] oxazin-1-ones was established. The reaction proceeds via the …