Review of the scientific understanding of radioactive waste at the US DOE Hanford site

RA Peterson, EC Buck, J Chun, RC Daniel… - … science & technology, 2018 - ACS Publications
This Critical Review reviews the origin and chemical and rheological complexity of
radioactive waste at the US Department of Energy Hanford Site. The waste, stored in …

In Situ 27Al NMR Spectroscopy of Aluminate in Sodium Hydroxide Solutions above and below Saturation with Respect to Gibbsite

TR Graham, M Dembowski, E Martinez-Baez… - Inorganic …, 2018 - ACS Publications
Aluminum hydroxide (Al (OH) 3, gibbsite) dissolution and precipitation processes in alkaline
environments play a commanding role in aluminum refining and nuclear waste processing …

Ab initio molecular dynamics reveal spectroscopic siblings and ion pairing as new challenges for elucidating prenucleation aluminum speciation

M Pouvreau, M Dembowski, SB Clark… - The Journal of …, 2018 - ACS Publications
The characterization of prenucleation species is essential to understand crystallization
mechanisms across many chemical systems and often involves the use of vibrational …

Gibbsite solubility in Hanford nuclear waste approached from above and below saturation

JG Reynolds, JK McCoskey… - Industrial & Engineering …, 2016 - ACS Publications
Liquid Hanford nuclear wastes are highly concentrated caustic aqueous electrolyte
solutions. They contain elevated dissolved aluminum concentrations compared to simple …

Ion–ion interactions enhance aluminum solubility in alkaline suspensions of nano-gibbsite (α-Al (OH) 3) with sodium nitrite/nitrate

M Dembowski, MM Snyder, CH Delegard… - Physical Chemistry …, 2020 - pubs.rsc.org
Despite widespread industrial importance, predicting metal solubilities in highly
concentrated, multicomponent aqueous solutions is difficult due to poorly understood ion …

Evidence for dawsonite in Hanford high-level nuclear waste tanks

JG Reynolds, GA Cooke, DL Herting… - Journal of hazardous …, 2012 - Elsevier
Gibbsite [Al (OH) 3] and boehmite (AlOOH) have long been assumed to be the most
prevalent aluminum-bearing minerals in Hanford high-level nuclear waste sludge. The …

The apparent reversal of the Law of Mass Action in concentrated multicomponent aqueous solutions

JG Reynolds, ET Nienhuis, ST Mergelsberg… - Journal of Molecular …, 2023 - Elsevier
Although it is well known that aqueous electrolyte solutions behave non-ideally, few are so
non-ideal that adding an electrolyte to a saturated solution with a common ion enhances …

A Pitzer Interaction Model for the NaNO3–NaNO2–NaOH–H2O System from 0 to 100 °C

JG Reynolds, R Carter, AR Felmy - Industrial & Engineering …, 2015 - ACS Publications
The solubility relations and water activities in NaNO3, NaNO2, and NaOH solutions are used
in many applications, including the management of alkaline high-level nuclear waste. Only …

The apparent solubility of aluminum (III) in Hanford high-level waste

JG Reynolds - Journal of Environmental Science and Health, Part A, 2012 - Taylor & Francis
The solubility of aluminum in Hanford nuclear waste impacts on the processability of the
waste by a number of proposed treatment options. For many years, Hanford staff has …

Conversion of Coarse Gibbsite Remaining in Hanford Nuclear Waste Tank Heels to Solid Sodium Aluminate [NaAl(OH)4·1.5H2O]

DL Herting, JG Reynolds… - Industrial & Engineering …, 2014 - ACS Publications
The Hanford Site near Richland, WA, has 177 high-level nuclear waste tanks containing 56
million gallons of waste derived from nuclear fuel reprocessing. The site is removing waste …