Insights into the solvation chemistry in liquid electrolytes for lithium-based rechargeable batteries

P Xiao, X Yun, Y Chen, X Guo, P Gao, G Zhou… - Chemical Society …, 2023 - pubs.rsc.org
Lithium-based rechargeable batteries have dominated the energy storage field and attracted
considerable research interest due to their excellent electrochemical performance. As …

Water-mediated ion pairing: Occurrence and relevance

NFA Van Der Vegt, K Haldrup, S Roke, J Zheng… - Chemical …, 2016 - ACS Publications
We present an overview of the studies of ion pairing in aqueous media of the past decade. In
these studies, interactions between ions, and between ions and water, are investigated with …

Regulating the electrical double layer with supramolecular cyclodextrin anions for dendrite-free zinc electrodeposition

L Wang, C Shen, C Huang, J Chen, J Zheng - ACS nano, 2023 - ACS Publications
The interfacial stability of a Zn battery is dependent on the electrical double layer (EDL) that
forms at the interface between the electrolyte and the Zn metal anode. A fundamental …

Mechanism of cations suppressing proton diffusion kinetics for electrocatalysis

XY Li, T Wang, YC Cai, ZD Meng, JW Nan… - Angewandte …, 2023 - Wiley Online Library
Proton transfer is crucial for electrocatalysis. Accumulating cations at electrochemical
interfaces can alter the proton transfer rate and then tune electrocatalytic performance …

Spectroscopic snapshots of the proton-transfer mechanism in water

CT Wolke, JA Fournier, LC Dzugan, MR Fagiani… - Science, 2016 - science.org
The Grotthuss mechanism explains the anomalously high proton mobility in water as a
sequence of proton transfers along a hydrogen-bonded (H-bonded) network. However, the …

Ultrahigh-rate and ultralong-life aqueous batteries enabled by special pair-dancing proton transfer

L Wang, J Yan, Y Hong, Z Yu, J Chen, J Zheng - Science Advances, 2023 - science.org
The design of Faradaic battery electrodes with high rate capability and long cycle life
comparable to those of supercapacitors is a grand challenge. Here, we bridge this …

Structure, organization, and heterogeneity of water-containing deep eutectic solvents

K Töpfer, A Pasti, A Das, SM Salehi… - Journal of the …, 2022 - ACS Publications
The spectroscopy and structural dynamics of a deep eutectic mixture (KSCN/acetamide) with
varying water content is investigated from 2D IR (with the C–N stretch vibration of the SCN …

Infrared probes for studying the structure and dynamics of biomolecules

H Kim, M Cho - Chemical reviews, 2013 - ACS Publications
The first step toward understanding most of the chemical and biological processes in
condensed phases is to accurately describe solute− solvent interaction energy and to …

Low-noise nanopore enables in-situ and label-free tracking of a trigger-induced DNA molecular machine at the single-molecular level

Z Zhu, X Duan, Q Li, R Wu, Y Wang… - Journal of the American …, 2020 - ACS Publications
Solid-state nanopores have shown special high potential in a label-free molecular assay,
structure identification, and target-index at the single-molecular level, even though …

Water dynamics and structure of highly concentrated LiCl solutions investigated using ultrafast infrared spectroscopy

SA Roget, KA Carter-Fenk… - Journal of the American …, 2022 - ACS Publications
In highly concentrated salt solutions, the water hydrogen bond (H-bond) network is
completely disrupted by the presence of ions. Water is forced to restructure as dictated by …