Sustainable Copolymer Synthesis from Carbon Dioxide and Butadiene

S Tang, BL Lin, I Tonks, JM Eagan, X Ni… - Chemical …, 2024 - ACS Publications
Carbon dioxide (CO2) has long been recognized as an ideal C1 feedstock comonomer for
producing sustainable materials because it is renewable, abundant, and cost-effective …

Key progresses of MOE key laboratory of macromolecular synthesis and functionalization in 2022

X Deng, K Chen, K Pang, X Liu, M Gao, J Ren… - Chinese Chemical …, 2024 - Elsevier
Abstract In 2022, The MOE Key Laboratory of Macromolecular Synthesis and
Functionalization in Zhejiang University had achieved several important results. First, a …

Ring‐opening Polymerization of Enantiopure Bicyclic Ether‐ester Monomers toward Closed‐loop Recyclable and Crystalline Stereoregular Polyesters via Chemical …

Z Li, D Zhao, Y Shen, Z Li - Angewandte Chemie International …, 2023 - Wiley Online Library
Although great successes have been achieved, the preparation of closed‐loop recyclable
polyesters with high working temperatures still remains as a big challenge. Herein, we …

Current Challenges and Perspectives in CO2-Based Polymers

Y Liu, XB Lu - Macromolecules, 2023 - ACS Publications
Carbon dioxide (CO2) is considered a renewable one-carbon building block for chemical
synthesis owing to its abundance, low toxicity, nonflammability, and availability. The …

Functional and Degradable Polyester-co-polyethers from CO2, Butadiene, and Epoxides

Y Zhao, X Zhang, Z Li, Z Li, S Tang - ACS Macro Letters, 2024 - ACS Publications
Carbon dioxide (CO2), as a renewable and nontoxic C1 feedstock, has been recognized as
an ideal comonomer to prepare sustainable materials. In this regard, substantial focus has …

How to Open the Ring of a Di‐ene‐Substituted‐δ‐Valerolactone: From Carbon Dioxide and 1, 3‐Butadiene to Functional Polyesters

K Chen, Y Mei, Z Zhang, J Ling, X Ni - ChemPlusChem, 2023 - Wiley Online Library
As a substituted‐δ‐valerolactone, α‐ethylidene‐δ‐vinyl‐δ‐valerolactone (EVL) provides a
method of utilizing carbon dioxide with 1, 3‐butadiene to produce functional polymers. Its di …

Random Terpolymer of Carbon Dioxide, Butadiene and Epoxides: Synthesis, Functionalization and Degradability

Z Wang, W Zheng, S Yue, K Chen… - Chinese Journal of …, 2024 - Wiley Online Library
Comprehensive Summary The utilization of carbon dioxide (CO2) as a C1 feedstock is
consistently attractive, especially in the preparation of sustainable polymeric materials. In …

Polyester Platform with High Refractive Indices and Closed-Loop Recyclability from CO2, 1,3-Butadiene, and Thiols

Z Zhang, T Shen, K Chen, J Zeng, Y Mei… - ACS Macro …, 2024 - ACS Publications
α-Ethylidene-δ-vinyl-δ-valerolactone (EVL) is the only intermediate to synthesize
copolymers of CO2 with 1, 3-butadiene whose ring-opening polymerization (ROP), however …

Ring-Opening Copolymerizations of a CO2-Derived δ-Valerolactone with ε-Caprolactone and l-Lactide

RJ Anderson, RL Fine, RM Rapagnani… - Macromolecules, 2024 - ACS Publications
Ring-opening random, gradient, and block copolymerizations of CO2-derived δ-
valerolactone 3-ethyl-6-vinyltetrahydro-2 H-pyran-2-one (EtVP) with ε-caprolactone (ε-CL) …

Anionic Conjugate Addition Oligomerization of Carbon Dioxide/Butadiene Derived Lactones

BJ Crawford, C Bochenek, LD Garcia Espinosa… - ACS Macro …, 2024 - ACS Publications
Nucleophilic and non-nucleophilic bases have been employed in anionic oligomerization of
unsaturated δ-valerolactone (3-ethylidene-6-vinyltetrahydro-2 H-pyran-2-one)(1). Compared …