Solvate-assisted grinding: metal solvates as solvent sources in mechanochemically driven organometallic reactions
HP DeGroot, TP Hanusa - Organometallics, 2021 - ACS Publications
Solvent effects in synthetic chemistry can be analyzed in various ways, but a possibly
counterintuitive approach is to remove the solvent entirely from the reaction environment …
counterintuitive approach is to remove the solvent entirely from the reaction environment …
[PDF][PDF] Structure determination from unindexed powder data from scratch by a global optimization approach using pattern comparison based on cross-correlation …
S Habermehl, C Schlesinger… - … Section B: Structural …, 2022 - journals.iucr.org
A method of ab initio crystal structure determination from powder diffraction data for organic
and metal–organic compounds, which does not require prior indexing of the powder pattern …
and metal–organic compounds, which does not require prior indexing of the powder pattern …
4-Cyanopyridine, a versatile mono-and bidentate ligand. Crystal structures of related coordination polymers determined by X-ray powder diffraction
4-Cyanopyridine (4-CNpy, also known as isonicotinonitrile) can act as a monodentate ligand
in transition metal complexes via the pyridine nitrogen atom (Npy), or as a bidentate ligand …
in transition metal complexes via the pyridine nitrogen atom (Npy), or as a bidentate ligand …
4-Cyanopyridine complexes [MX 2 (4-CNpy) x] n (with X= Cl, Br and x= 1, 2): Crystal structures, thermal properties and a comparison with [MX 2 (3-CNpy) x] n …
M Heine, L Fink, MU Schmidt - CrystEngComm, 2020 - pubs.rsc.org
Eleven new complexes [MX2 (4-CNpy) x](n) with M= Mn, Fe, Co, Ni, Cu, and Zn, X= Cl and
Br, 4-CNpy= 4-cyanopyridine, and x= 1 and 2 have been prepared and their structures were …
Br, 4-CNpy= 4-cyanopyridine, and x= 1 and 2 have been prepared and their structures were …
Hybrid Organic–Inorganic Crystals of [Methylhydrazinium]MIICl3 (MII = Co, Ni, Mn)
We report the synthesis and investigation of the physicochemical properties of novel one-
dimensional hybrid organic–inorganic chlorides templated by the methylhydrazinium …
dimensional hybrid organic–inorganic chlorides templated by the methylhydrazinium …
3-Cyanopyridine as a bridging and terminal ligand in coordination polymers
M Heine, L Fink, MU Schmidt - CrystEngComm, 2018 - pubs.rsc.org
3-Cyanopyridine (3-CNpy) can act as a bridging or terminal ligand in transition metal
coordination polymers. The compounds [MIIBr2 (3-CNpy) 4] with M= Mn, Fe, Co, Ni (1a–4a) …
coordination polymers. The compounds [MIIBr2 (3-CNpy) 4] with M= Mn, Fe, Co, Ni (1a–4a) …
Coordination compounds built up from M II Cl 2 and 3-cyanopyridine: double chains, single chains and isolated complexes
M Heine, L Fink, MU Schmidt - CrystEngComm, 2019 - pubs.rsc.org
The coordination polymers [MIICl2 (3-CNpy) 2] n, with 3-CNpy= 3-cyanopyridine and MII=
Mn, Fe, Co, Ni, Cu, Zn (1a–6a), were synthesised and the related structures determined by X …
Mn, Fe, Co, Ni, Cu, Zn (1a–6a), were synthesised and the related structures determined by X …
Synthesis, Structures, Thermal and Luminescence Properties of Zn and Cd Halide Coordination Polymers with 2‐Cyanopyrazine
I Jess, T Neumann, H Terraschke… - Zeitschrift für …, 2020 - Wiley Online Library
Reaction of MX2 (M= Cd, Zn; X= Cl, Br, I) with 2‐cyanopyrazine leads to the formation of
compounds with the composition CdX2 (2‐cyanopyrazine) 2 (X= Cl; CdCl, X= Br; CdBr and …
compounds with the composition CdX2 (2‐cyanopyrazine) 2 (X= Cl; CdCl, X= Br; CdBr and …
[PDF][PDF] Crystal structure of [bis (2-aminoethyl-κN)(2-{[4-(trifluoromethyl) benzylidene] amino} ethyl) amine-κN] dichloridocopper (II)
KA Bussey, AR Cavalier, ME Mraz… - Acta …, 2016 - journals.iucr.org
The CuII atom in the title compound,[CuCl2 (C14H21F3N4)], adopts a coordination
geometry that is between distorted square-based pyramidal and very Jahn–Teller-elongated …
geometry that is between distorted square-based pyramidal and very Jahn–Teller-elongated …