The use of aurophilic and other metal–metal interactions as crystal engineering design elements to increase structural dimensionality

MJ Katz, K Sakai, DB Leznoff - Chemical Society Reviews, 2008 - pubs.rsc.org
Research in the field of supramolecular chemistry has rapidly grown in recent years due to
the generation of fascinating structural topologies and their associated physical properties …

Polymorphism of Zn[Au(CN)2]2 and Its Luminescent Sensory Response to NH3 Vapor

MJ Katz, T Ramnial, HZ Yu… - Journal of the American …, 2008 - ACS Publications
Four polymorphic forms of the complex Zn [Au (CN) 2] 2 have been synthesized and both
structurally and spectroscopically characterized. In each of the four polymorphs, a zinc …

Gold− Gold Interactions as Crystal Engineering Design Elements in Heterobimetallic Coordination Polymers

DB Leznoff, BY Xue, RJ Batchelor… - Inorganic …, 2001 - ACS Publications
A series of coordination polymers containing Cu (II) and [Au (CN) 2]-units has been
prepared. Most of their structures incorporate attractive gold− gold interactions, thus …

Three novel silver complexes with ligand-unsupported argentophilic interactions and their luminescent properties

X Liu, Guo, ML Fu, XH Liu, MS Wang… - Inorganic …, 2006 - ACS Publications
Three novel silver complexes, namely,[Ag5 (CN) 5 (bipy) 2] n (1) with a 1-D to 3-D
architecture constructed through ligand-unsupported argentophilic interactions,[Ag5 (SCN) 4 …

Heterobimetallic Coordination Polymers Incorporating [M(CN)2]- (M = Cu, Ag) and [Ag2(CN)3]- Units:  Increasing Structural Dimensionality via M−M' and M···NC …

CJ Shorrock, BY Xue, PB Kim, RJ Batchelor… - Inorganic …, 2002 - ACS Publications
A series of new heterometallic coordination polymers has been prepared from the reaction
of metal− ligand cations and KAg (CN) 2 units. Many of these contain silver− silver …

Architecture Dependence on the Steric Constrains of the Ligand in Cyano-Bridged Copper (I) and Copper (II)− Copper (I) Mixed-Valence Polymer Compounds …

E Colacio, R Kivekäs, F Lloret, M Sunberg… - Inorganic …, 2002 - ACS Publications
A family of cyano-bridged copper (II)− copper (I) mixed-valence polymers containing
diamine ligands of formula [Cu (pn) 2][Cu2 (CN) 4](1, pn= 1, 2-propanediamine),[Cu2 (CN) 3 …

Synthesis, structure and magnetic properties of 2-D and 3-D [cation]{M [Au (CN) 2] 3}(M= Ni, Co) coordination polymers

J Lefebvre, D Chartrand, DB Leznoff - Polyhedron, 2007 - Elsevier
In order to study the templating effect of the cation and the resulting impact on the magnetic
properties, reactions of M (II) salts with [cation][Au (CN) 2] were conducted, yielding a series …

Unsupported intermolecular argentophilic interaction in the dimer of trinuclear silver (I) 3, 5-diphenylpyrazolates

AA Mohamed, LM Pérez, JP Fackler Jr - Inorganica chimica acta, 2005 - Elsevier
The reaction of a solution of sodium 3, 5-diphenylpyrazolate, Na [Ph2pz], with Ag (tht) NO3
in dichloromethane affords thin needles of unsolvated and light-stable dimer of trimers [Ag3 …

Synthesis, structure and magnetic properties of 3D interpenetrating nets of M (pyrazine)[Au (CN) 2] 2 (M= Cu, Ni, Co) supported by aurophilic interactions

DB Leznoff, BY Xue, CL Stevens, A Storr… - Polyhedron, 2001 - Elsevier
New inorganic coordination polymers of the form M (pyrazine)[Au (CN) 2] 2 (M= Cu (1); Ni
(2); Co (3)) have been prepared and the copper (II) analogue structurally characterised. The …

Structure and multinuclear solid-state NMR of a highly birefringent lead− gold cyanide coordination polymer

MJ Katz, PM Aguiar, RJ Batchelor… - Journal of the …, 2006 - ACS Publications
The coordination polymer Pb (H2O)[Au (CN) 2] 2 (1) was synthesized by the reaction of KAu
(CN) 2 and Pb (NO3) 2. The structure contains 1-D chains of lead (II)− OH2 linked via Au …