Epihalohydrins in organic synthesis

GS Singh, K Mollet, M D'hooghe… - Chemical Reviews, 2013 - ACS Publications
Epihalohydrins [2-(halomethyl) oxiranes, 1, 2-epoxy-3-halopropanes](Figure 1) are well-
known versatile synthons and important reagents in the realm of organic synthesis …

Nucleophilic ring-opening of epoxides: trends in β-substituted alcohols synthesis

M Fallah-Mehrjardi, AR Kiasat, K Niknam - Journal of the Iranian Chemical …, 2018 - Springer
The present review deals with the ring-opening of epoxides by various carbon, nitrogen,
oxygen, halogen, and sulfur-containing nucleophiles, which most of the resulting products …

Mesoporous Zr-Beta zeolites prepared by a post-synthetic strategy as a robust Lewis acid catalyst for the ring-opening aminolysis of epoxides

B Tang, W Dai, X Sun, G Wu, N Guan, M Hunger… - Green Chemistry, 2015 - pubs.rsc.org
Mesoporous zirconosilicate, stannosilicate, and titanosilicate with the BEA structure
framework have been prepared from the commercially available Beta zeolite via acid …

Efficient conversion of glucose to methyl lactate with Sn-USY: retro-aldol activity promotion by controlled ion exchange

JM Jimenez-Martin, A Orozco-Saumell… - ACS Sustainable …, 2022 - ACS Publications
Sn-USY materials have been prepared through an optimized post-synthetic catalytic
metalation procedure. These zeolites displayed, upon ion exchange with alkaline metals, an …

Highly efficient nanocrystalline zirconosilicate catalysts for the aminolysis, alcoholysis, and hydroamination reactions

R Kore, R Srivastava, B Satpati - ACS Catalysis, 2013 - ACS Publications
Nanocrystalline zirconosilicates and titanosilicates with MFI framework structure were
hydrothermally synthesized by the addition of organosilanes in the synthesis composition of …

Coordinatively unsaturated sites in zeolite matrix: Construction and catalysis

W Li, L Sun, L Xie, X Deng, N Guan, L Li - Chinese Journal of Catalysis, 2019 - Elsevier
Zeolites with ordered porous structure of molecular size are widely employed as commercial
adsorbents and catalysts. On the other hand, the zeolite matrix is regarded as an ideal …

Activation and reactivity of epoxides on solid acid catalysts

L Saikia, JK Satyarthi, D Srinivas, P Ratnasamy - Journal of Catalysis, 2007 - Elsevier
The aminolysis of epoxides over novel solid catalysts (Brönsted-acidic SBA-15
functionalized with propylsulfonic acid and Lewis-acidic Ti-MCM-41) is reported. The acidic …

Synthesis and Catalytic Applications of Advanced Sn‐and Zr‐Zeolites Materials

X Liu, Z Zhu - Advanced Science, 2024 - Wiley Online Library
The incorporation of isolated Sn (IV) and Zr (IV) ions into silica frameworks is attracting
widespread attention, which exhibits remarkable catalytic performance (conversion …

Solvent-free carbonylation of glycerol with urea using metal loaded MCM-41 catalysts

SE Kondawar, AS Potdar, CV Rode - RSC advances, 2015 - pubs.rsc.org
Reacting glycerol with urea is the most attractive option for the production of glycerol
carbonate (GC) as it utilizes two inexpensive chemicals readily available in the chemical …

Post-synthesis of Zr-MOR as a robust solid acid catalyst for the ring-opening aminolysis of epoxides

B Tang, WC Song, SY Li, EC Yang… - New Journal of Chemistry, 2018 - pubs.rsc.org
Zirconosilicate with the MOR topology (Zr-MOR) was successfully prepared using a two-step
post-synthesis strategy from pre-dealumination of a H-MOR zeolite and subsequent dry …