[HTML][HTML] Solid-state nuclear magnetic resonance spectroscopy of cements

B Walkley, JL Provis - Materials Today Advances, 2019 - Elsevier
Cement is the ubiquitous material upon which modern civilisation is built, providing long-
term strength, impermeability and durability for housing and infrastructure. The fundamental …

Alumina: discriminative analysis using 3D correlation of solid-state NMR parameters

CV Chandran, CEA Kirschhock… - Chemical Society …, 2019 - pubs.rsc.org
Synthetic transition aluminas (χ, κ, θ, γ, δ, η, ρ) exhibit unique adsorptive and catalytic
properties leading to numerous practical applications. Generated by thermal transformation …

The atomic-level structure of cementitious calcium aluminate silicate hydrate

A Kunhi Mohamed, P Moutzouri… - Journal of the …, 2020 - ACS Publications
Despite use of blended cements containing significant amounts of aluminum for over 30
years, the structural nature of aluminum in the main hydration product, calcium aluminate …

A quantitative study of 27Al MAS NMR in crystalline YAG

D Massiot, C Bessada, JP Coutures… - Journal of Magnetic …, 1990 - Elsevier
A quantitative 27 Al NMR analysis of yttrium aluminum garnet. involving a complete
computation of the quadrupolar interaction in MAS conditions, has been performed. Results …

Isotropic NMR spectra of half-integer quadrupolar nuclei using satellite transitions and magic-angle spinning

Z Gan - Journal of the American Chemical Society, 2000 - ACS Publications
Nuclear magnetic resonance (NMR) spectroscopy has become an important tool for
structural characterization of many important materials such as minerals, ceramics, glasses …

Quantification of five-and six-coordinated aluminum ions in aluminosilicate and fluoride-containing glasses by high-field, high-resolution 27Al NMR

JF Stebbins, S Kroeker, SK Lee, TJ Kiczenski - Journal of Non-Crystalline …, 2000 - Elsevier
Aluminum cation sites with five ([5] Al) or six ([6] Al) anion neighbors are minor species in
aluminosilicate glasses that are interesting in models of structure, diffusion, and viscous …

Recent advances in experimental solid state NMR methodology for half-integer spin quadrupolar nuclei

ME Smith, ERH van Eck - Progress in nuclear magnetic resonance …, 1999 - Elsevier
1. Introduction.................................................................. 160 2. Nuclear interactions.........................
................................... 161 3. Background experimental principles …

A practical guide to solid-state NMR of half-integer quadrupolar nuclei with some applications to disordered systems

APM Kentgens - Geoderma, 1997 - Elsevier
The practical aspects for obtaining useful NMR spectra of half-integer quadrupolar nuclei in
diamagnetic solids are discussed in some detail. The general appearance of the Magic …

Cooperative mechanisms of oxygen vacancy stabilization and migration in the isolated tetrahedral anion Scheelite structure

X Yang, AJ Fernández-Carrión, J Wang… - Nature …, 2018 - nature.com
Tetrahedral units can transport oxide anions via interstitial or vacancy defects owing to their
great deformation and rotation flexibility. Compared with interstitial defects, vacancy …

A quantitative study of the C3A hydration

S Joseph, J Skibsted, Ö Cizer - Cement and Concrete Research, 2019 - Elsevier
The effect of fineness, gypsum content and water–cement (w/c) ratio on the hydration of C 3
A systems have been quantitatively investigated using a combination of experimental …