Phosphine organocatalysis

H Guo, YC Fan, Z Sun, Y Wu, O Kwon - Chemical reviews, 2018 - ACS Publications
The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

Phosphine-catalyzed asymmetric organic reactions

H Ni, WL Chan, Y Lu - Chemical reviews, 2018 - ACS Publications
Asymmetric phosphine catalysis showcasing remarkable progress over the past two
decades has emerged as a key synthetic platform for the creation of molecular frameworks …

Synthesis of heterocyclic compounds through nucleophilic phosphine catalysis

Y Huang, J Liao, W Wang, H Liu, H Guo - Chemical Communications, 2020 - pubs.rsc.org
Nucleophilic phosphine catalysis is a practical and powerful tool for the synthesis of various
heterocyclic compounds with the advantages of environmentally friendly, metal-free, and …

Phosphine‐catalyzed enantioselective dearomative [3+ 2]‐cycloaddition of 3‐nitroindoles and 2‐nitrobenzofurans

H Wang, J Zhang, Y Tu, J Zhang - Angewandte Chemie, 2019 - Wiley Online Library
Over the past years, the metal‐catalyzed dearomative cycloaddition of 3‐nitroindoles and 2‐
nitrobenzofurans have emerged as a powerful protocol to construct chiral fused heterocyclic …

Chiral monophosphorus ligands for asymmetric catalytic reactions

W Fu, W Tang - ACS Catalysis, 2016 - ACS Publications
Chiral monophosphorus ligands are playing an important role for the recent advances in
asymmetric catalysis. This review summarizes the latest progress in various asymmetric …

Crystallography of encapsulated molecules

K Rissanen - Chemical Society Reviews, 2017 - pubs.rsc.org
The crystallography of supramolecular host–guest complexes is reviewed and discussed as
a part of small molecule crystallography. In these complexes, the host binds the guests …

Asymmetric Synthesis of Spirocyclic β‐Lactams through Copper‐Catalyzed Kinugasa/Michael Domino Reactions

T Shu, L Zhao, S Li, XY Chen… - Angewandte Chemie …, 2018 - Wiley Online Library
The first copper‐catalyzed highly chemo‐, regio‐, diastereo‐, and enantioselective
Kinugasa/Michael domino reaction for the desymmetrization of prochiral cyclohexadienones …

Enantioselective Catalysis by the Umpolung of Conjugate Acceptors Involving N-Heterocyclic Carbene or Organophosphine 1, 4-Addition

Y Nakano, JT Maddigan-Wyatt… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Conjugate acceptors are one of the most common electrophilic functional
groups in organic synthesis. While useful in a diverse range of transformations, their …

Exploration of flow reaction conditions using machine-learning for enantioselective organocatalyzed Rauhut–Currier and [3+ 2] annulation sequence

M Kondo, HDP Wathsala, M Sako, Y Hanatani… - Chemical …, 2020 - pubs.rsc.org
A highly atom-economical enantioselective organocatalyzed Rauhut–Currier and [3+ 2]
annulation sequence has been established by using a flow system. Suitable flow conditions …

Stereocontrolled transformations of cyclohexadienone derivatives to access stereochemically rich and natural product-inspired architectures

TH Al-Tel, V Srinivasulu, M Ramanathan… - Organic & …, 2020 - pubs.rsc.org
The last two decades or so have witnessed an upsurge in defining the art of designing
complex natural products and nature-inspired molecules. Throughout these decades …