Confinement-controlled aqueous chemistry within nanometric slit pores: Focus review

D Munoz-Santiburcio, D Marx - Chemical Reviews, 2021 - ACS Publications
In this Focus Review, we put the spotlight on very recent insights into the fascinating world of
wet chemistry in the realm offered by nanoconfinement of water in mechanically rather rigid …

Can electric fields drive chemistry for an aqueous microdroplet?

H Hao, I Leven, T Head-Gordon - Nature communications, 2022 - nature.com
Reaction rates of common organic reactions have been reported to increase by one to six
orders of magnitude in aqueous microdroplets compared to bulk solution, but the reasons for …

The emerging chemistry of self-electrified water interfaces

F Galembeck, LP Santos, TAL Burgo… - Chemical Society …, 2024 - pubs.rsc.org
Water is known for dissipating electrostatic charges, but it is also a universal agent of matter
electrification, creating charged domains in any material contacting or containing it. This new …

Water-mediated heterogeneously catalyzed reactions

G Li, B Wang, DE Resasco - Acs Catalysis, 2019 - ACS Publications
Nature takes advantage of the pervasive presence of water to control many enzymatic
reactions by utilizing the unique properties of water, which in turn help regulating reaction …

Environmental applications of engineered materials with nanoconfinement

S Zhang, T Hedtke, X Zhou, M Elimelech… - ACS ES&T …, 2021 - ACS Publications
Engineered nanoporous materials have been extensively employed in the environmental
field to take advantage of increased surface area and tunable size exclusion. Beyond those …

A critical analysis of electrospray techniques for the determination of accelerated rates and mechanisms of chemical reactions in droplets

G Rovelli, MI Jacobs, MD Willis, RJ Rapf… - Chemical …, 2020 - pubs.rsc.org
Electrospray and Electrosonic Spray Ionization Mass Spectrometry (ESI-MS and ESSI-MS)
have been widely used to report evidence that many chemical reactions in micro-and nano …

Simple model for the electric field and spatial distribution of ions in a microdroplet

CF Chamberlayne, RN Zare - The Journal of chemical physics, 2020 - pubs.aip.org
It is well established that the chemistry in microdroplets has been found to be radically
different from reactions in bulk, particularly in the case of water. It has also been established …

A kinetic description of how interfaces accelerate reactions in micro-compartments

KR Wilson, AM Prophet, G Rovelli, MD Willis… - Chemical …, 2020 - pubs.rsc.org
A kinetic expression is derived to explain how interfaces alter bulk chemical equilibria and
accelerate reactions in micro-compartments. This description, aided by the development of a …

Strong electric field force at the air/water interface drives fast sulfate production in the atmosphere

Y Liu, Q Ge, T Wang, R Zhang, K Li, K Gong, L Xie… - Chem, 2024 - cell.com
How tiny aqueous aerosol droplets significantly accelerate the atmospheric multiphase
reaction remains an open question. Here, we show both experimental and theoretical …

Chemical kinetics in microdroplets

KR Wilson, AM Prophet - Annual Review of Physical Chemistry, 2024 - annualreviews.org
Micrometer-sized compartments play significant roles in driving heterogeneous
transformations within atmospheric and biochemical systems as well as providing vehicles …