Reaction rates of common organic reactions have been reported to increase by one to six orders of magnitude in aqueous microdroplets compared to bulk solution, but the reasons for …
Water is known for dissipating electrostatic charges, but it is also a universal agent of matter electrification, creating charged domains in any material contacting or containing it. This new …
Nature takes advantage of the pervasive presence of water to control many enzymatic reactions by utilizing the unique properties of water, which in turn help regulating reaction …
Engineered nanoporous materials have been extensively employed in the environmental field to take advantage of increased surface area and tunable size exclusion. Beyond those …
Electrospray and Electrosonic Spray Ionization Mass Spectrometry (ESI-MS and ESSI-MS) have been widely used to report evidence that many chemical reactions in micro-and nano …
CF Chamberlayne, RN Zare - The Journal of chemical physics, 2020 - pubs.aip.org
It is well established that the chemistry in microdroplets has been found to be radically different from reactions in bulk, particularly in the case of water. It has also been established …
A kinetic expression is derived to explain how interfaces alter bulk chemical equilibria and accelerate reactions in micro-compartments. This description, aided by the development of a …
How tiny aqueous aerosol droplets significantly accelerate the atmospheric multiphase reaction remains an open question. Here, we show both experimental and theoretical …
KR Wilson, AM Prophet - Annual Review of Physical Chemistry, 2024 - annualreviews.org
Micrometer-sized compartments play significant roles in driving heterogeneous transformations within atmospheric and biochemical systems as well as providing vehicles …