Over the past few decades, there have been major developments in transition metal-
catalyzed asymmetric cyclization reactions, enabling the convenient access to a wide …

Palladium‐catalyzed decarboxylative cycloadditions have emerged as highly effective
methods for constructing structurally diverse carbo‐and heterocycles because of the …

While cycloaddition reactions of bicyclobutanes (BCBs) have emerged as a potent method
for synthesizing (hetero-) bicyclo [n. 1.1] alkanes (usually n≤ 3), their utilization in the …

A Pd-catalyzed asymmetric higher-order dipolar cycloaddition between allenyl carbonates
and azadienes is achieved by exploiting novel alkylidene-π-allyl-Pd dipoles. This research …

Ligand-directed divergent synthesis (LDS) is an important synthetic tool for the preparation
of structurally diverse organic molecules without tedious steps to modify substrates. Herein …

A palladium-catalyzed enantioselective α-allylation of deconjugated butenolides with aza-π-
allylpalladium 1, 4-diploes, in situ generated from palladium-mediated decarboxylation of …

Inspired by a fungicide, we designed 5-vinyloxazolidine-2, 4-diones as new precursors of π-
allylpalladium zwitterionic intermediates and developed palladium-catalyzed asymmetric …

In the past few years, Pd-catalyzed annulation reactions through zwitterionic π-allyl
palladium intermediates have been extensively investigated. Meanwhile, zwitterionic π-allyl …

Palladium-catalyzed cycloaddition reactions via Pd-π-allyl zwitterions have been
established as significant synthetic transformations to enable numerous carbon-or …

Pyrazolones and pyrazoles, featuring nitrogen–nitrogen bonds, are two of the most
important classes of heterocycles, owing to their widespread occurrence in medicinal …