[HTML][HTML] The tale of alkyl-and acylcobalt carbonyls
The almost centennary history of alkyl-and acylcobalt carbonyls started with preparative and
structural interest in these particular compounds, but the attention also soon included …
structural interest in these particular compounds, but the attention also soon included …
Investigations of tri-t-butyl tin hydride complexes of transition metals in small molecule activation and catalysis
Transition metal complexes containing the sterically encumbered SnBu t 3 group are the
focus of this brief review. The ability of tin compounds to modify both heterogeneous and …
focus of this brief review. The ability of tin compounds to modify both heterogeneous and …
Synthesis of [Pt(SnBut3)(IBut)(μ-H)]2, a Coordinatively Unsaturated Dinuclear Compound which Fragments upon Addition of Small Molecules to Form Mononuclear …
The reaction of Pt (COD) 2 with one equivalent of tri-tert-butylstannane, But3SnH, at room
temperature yields Pt (SnBut3)(COD)(H)(3) in quantitative yield. In the presence of excess …
temperature yields Pt (SnBut3)(COD)(H)(3) in quantitative yield. In the presence of excess …
Pendant Alkyl and Aryl Groups on Tin Control Complex Geometry and Reactivity with H2/D2 in Pt(SnR3)2(CNBut)2 (R = But, Pri, Ph, Mesityl)
The complex Pt (SnBut3) 2 (CNBut) 2 (H) 2, 1, was obtained from the reaction of Pt (COD) 2
and But3SnH, followed by addition of CNBut. The two hydride ligands in 1 can be …
and But3SnH, followed by addition of CNBut. The two hydride ligands in 1 can be …
Preparation and reactivity of stannyl and germyl complexes of cobalt
G Albertin, S Antoniutti, J Castro - Journal of Organometallic Chemistry, 2012 - Elsevier
Trichlorostannyl complex Co (SnCl3)(CO) 2 (PPh3) 2 (1) was prepared by allowing the
chloro compound CoCl (CO) 2 (PPh3) 2 to react with SnCl2· 2H2O. Instead, treatment of the …
chloro compound CoCl (CO) 2 (PPh3) 2 to react with SnCl2· 2H2O. Instead, treatment of the …
Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)3]–
J Klösener, M Wiesemann, B Neumann… - European Journal of …, 2018 - Wiley Online Library
In this contribution the syntheses of transition metal complexes of the electron‐withdrawing
Sn (C2F5) 3 ligand are presented. The reaction of HSn (C2F5) 3 with organometallics LnM …
Sn (C2F5) 3 ligand are presented. The reaction of HSn (C2F5) 3 with organometallics LnM …
Photochemical synthesis and radical generation of the nickel-tin dimer [Ni (SnBut3)(CNBut) 2 (CO)] 2
Ni (COD) 2 reacts with Bu t 3 SnH and CNBu t at room temperature to afford the trigonal
bipyramidal complex Ni (SnBu t 3) 2 (CNBu t) 3, 3. Exposing a solution of 3 to CO gas results …
bipyramidal complex Ni (SnBu t 3) 2 (CNBu t) 3, 3. Exposing a solution of 3 to CO gas results …
[图书][B] Synthesis and characterization of transition metal complexes with bulky tin ligands for application in small molecule activation
V Yempally - 2012 - search.proquest.com
The role of bulky tin ligands in the stabilization of transition metal complexes with electronic
unsaturation has been studied to understand the mode of binding of small molecules at an …
unsaturation has been studied to understand the mode of binding of small molecules at an …
Hydrosilylation of Imines Using a Ni (0) Catalyst
DP Spence - 2016 - escholarship.org
The following herein introduces a Ni (0) catalyst that effectively does hydrosilylation of
imines to form the corresponding aminosilanes which are of interest in the electronics …
imines to form the corresponding aminosilanes which are of interest in the electronics …
Small molecule activation at nickel and platinum centers containing bulky tin and tempo radical ligands
A Koppaka - 2014 - search.proquest.com
Metal complexes have long been recognized as fundamental in activating simple small
molecules, which provide low-barrier reaction pathways through binding. One way to make …
molecules, which provide low-barrier reaction pathways through binding. One way to make …