Strategies toward high-temperature lanthanide-based single-molecule magnets
L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …
magnetization blocking at the level of one molecule. In this paper, we examine the physical …
Ferrotoroidic ground state in a heterometallic {CrIIIDyIII6} complex displaying slow magnetic relaxation
KR Vignesh, A Soncini, SK Langley… - Nature …, 2017 - nature.com
Toroidal quantum states are most promising for building quantum computing and
information storage devices, as they are insensitive to homogeneous magnetic fields, but …
information storage devices, as they are insensitive to homogeneous magnetic fields, but …
Coordination‐Cluster‐Based Molecular Magnetic Refrigerants
S Zhang, P Cheng - The Chemical Record, 2016 - Wiley Online Library
Coordination polymers serving as molecular magnetic refrigerants have been attracting
great interest. In particular, coordination cluster compounds that demonstrate their apparent …
great interest. In particular, coordination cluster compounds that demonstrate their apparent …
Realization of toroidal magnetic moments in heterometallic 3d–4f metallocycles
J Wu, XL Li, M Guo, L Zhao, YQ Zhang… - Chemical …, 2018 - pubs.rsc.org
Realization of toroidal magnetic moments in heterometallic 3d–4f metallocycles - Chemical
Communications (RSC Publishing) DOI:10.1039/C7CC09391H Royal Society of Chemistry …
Communications (RSC Publishing) DOI:10.1039/C7CC09391H Royal Society of Chemistry …
Role of the Diamagnetic Zinc (II) Ion in Determining the Electronic Structure of Lanthanide Single‐Ion Magnets
Four complexes containing DyIII and PrIII ions and their LnIII–ZnII analogs have been
synthesized in order to study the influence that a diamagnetic ZnII ion has on the electronic …
synthesized in order to study the influence that a diamagnetic ZnII ion has on the electronic …
Quenching the Quantum Tunneling of Magnetization in Heterometallic Octanuclear {TMIII4DyIII4} (TM=Co and Cr) Single‐Molecule Magnets by Modification of the …
KR Vignesh, SK Langley, KS Murray… - … –A European Journal, 2017 - Wiley Online Library
We report the synthesis, structural characterisation, magnetic properties and provide an ab
initio analysis of the magnetic behaviour of two new heterometallic octanuclear coordination …
initio analysis of the magnetic behaviour of two new heterometallic octanuclear coordination …
Slow Magnetic Relaxation and Single‐Molecule Toroidal Behaviour in a Family of Heptanuclear {CrIIILnIII6} (Ln=Tb, Ho, Er) Complexes
KR Vignesh, SK Langley, A Swain… - Angewandte …, 2018 - Wiley Online Library
The synthesis, magnetic properties, and theoretical studies of three heterometallic
{CrIIILnIII6}(Ln= Tb, Ho, Er) complexes, each containing a metal topology consisting of two …
{CrIIILnIII6}(Ln= Tb, Ho, Er) complexes, each containing a metal topology consisting of two …
3D isomorphous lanthanide coordination polymers displaying magnetic refrigeration, slow magnetic relaxation and tunable proton conduction
Four new isostructural lanthanide-based three-dimensional (3D) coordination polymers
(CPs),{[Ln4 (OH) 4 (L) 2 (H2O) 8]· 4.6 H2O· 1.4 CH3CN} n (Ln3+= Gd3+ (1), Dy3+ (2), Ho3+ …
(CPs),{[Ln4 (OH) 4 (L) 2 (H2O) 8]· 4.6 H2O· 1.4 CH3CN} n (Ln3+= Gd3+ (1), Dy3+ (2), Ho3+ …
Role of single-ion anisotropy and magnetic exchange interactions in suppressing zero-field tunnelling in {3d-4f} single molecule magnets
T Gupta, MF Beg, G Rajaraman - Inorganic Chemistry, 2016 - ACS Publications
Extensive ab initio CASSCF/RASSI-SO/SINGLE_ANISO/POLY_ANISO calculations have
been undertaken on eight structurally similar previously synthesized [CuII (L)(C3H6O) LnIII …
been undertaken on eight structurally similar previously synthesized [CuII (L)(C3H6O) LnIII …
Homometallic DyIII Complexes of Varying Nuclearity from 2 to 21: Synthesis, Structure, and Magnetism
The synthesis, structure, and magnetic properties of four DyIII coordination compounds
isolated as [Dy2 (LH2) 2 (μ2‐η1: η1‐Piv)] Cl⋅ 2 MeOH⋅ H2O (1),[Dy4 (LH) 2 (μ3‐OH) 2 …
isolated as [Dy2 (LH2) 2 (μ2‐η1: η1‐Piv)] Cl⋅ 2 MeOH⋅ H2O (1),[Dy4 (LH) 2 (μ3‐OH) 2 …