Quantum tunneling of magnetization and related phenomena in molecular materials

D Gatteschi, R Sessoli - Angewandte Chemie International …, 2003 - Wiley Online Library
Molecules comprising a large number of coupled paramagnetic centers are attracting much
interest because they may show properties which are intermediate between those of simple …

Zero-field splitting in metal complexes

R Boča - Coordination chemistry reviews, 2004 - Elsevier
Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the
components of the Λ-tensor involving only the matrix elements of the angular momentum …

The drosophila of single-molecule magnetism:[Mn 12 O 12 (O 2 CR) 16 (H 2 O) 4]

R Bagai, G Christou - Chemical Society Reviews, 2009 - pubs.rsc.org
Single-molecule magnets (SMMs) are individual molecules that can function as nanoscale
magnetic particles. The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= Me, Et, etc.) family of …

Synthesis of 3d Metallic Single-Molecule Magnets

G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

Evidence for Single-Chain Magnet Behavior in a MnIII−NiII Chain Designed with High Spin Magnetic Units:  A Route to High Temperature Metastable Magnets

R Clérac, H Miyasaka, M Yamashita… - Journal of the American …, 2002 - ACS Publications
We herein present the synthesis, crystal structure, and magnetic properties of a new
heterometallic chain of MnIII and NiII ions,[Mn2 (saltmen) 2Ni (pao) 2 (py) 2](ClO4) 2 …

Single-molecule magnets: a molecular approach to nanoscale magnetic materials

G Christou - Polyhedron, 2005 - Elsevier
A brief survey is provided of single-molecule magnets (SMMs), or molecular nanomagnets.
The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= various) family of SMMs continues to be the …

Quantentunneln der Magnetisierung und verwandte Phänomene in molekularen Materialien

D Gatteschi, R Sessoli - Angewandte Chemie, 2003 - Wiley Online Library
Moleküle mit einer großen Zahl gekoppelter paramagnetischer Zentren werden gegenwärtig
intensiv erforscht. Man hofft auf Eigenschaften zu treffen, die zwischen denen isolierter …

Mixed-valent Mn supertetrahedra and planar discs as enhanced magnetic coolers

M Manoli, A Collins, S Parsons, A Candini… - Journal of the …, 2008 - ACS Publications
The syntheses and structures of two decametallic mixed-valent Mn supertetrahedra using 2-
amino-2-methyl-1, 3-propanediol (ampH2), two decametallic mixed-valent Mn planar discs …

Single-Molecule Magnets:  A New Family of Mn12 Clusters of Formula [Mn12O8X4(O2CPh)8L6]

C Boskovic, EK Brechin, WE Streib… - Journal of the …, 2002 - ACS Publications
The reaction of (NBu n 4)[Mn8O6Cl6 (O2CPh) 7 (H2O) 2](1) with 2-(hydroxymethyl) pyridine
(hmpH) or 2-(hydroxyethyl) pyridine (hepH) gives the MnII2MnIII10 title compounds …

Encapsulation of single-molecule magnets in carbon nanotubes

M del Carmen Giménez-López, F Moro… - Nature …, 2011 - nature.com
Next-generation electronic, photonic or spintronic devices will be based on nanoscale
functional units, such as quantum dots, isolated spin centres or single-molecule magnets …