R Boča - Coordination chemistry reviews, 2004 - Elsevier
Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Λ-tensor involving only the matrix elements of the angular momentum …
Single-molecule magnets (SMMs) are individual molecules that can function as nanoscale magnetic particles. The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= Me, Et, etc.) family of …
G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …
R Clérac, H Miyasaka, M Yamashita… - Journal of the American …, 2002 - ACS Publications
We herein present the synthesis, crystal structure, and magnetic properties of a new heterometallic chain of MnIII and NiII ions,[Mn2 (saltmen) 2Ni (pao) 2 (py) 2](ClO4) 2 …
A brief survey is provided of single-molecule magnets (SMMs), or molecular nanomagnets. The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= various) family of SMMs continues to be the …
D Gatteschi, R Sessoli - Angewandte Chemie, 2003 - Wiley Online Library
Moleküle mit einer großen Zahl gekoppelter paramagnetischer Zentren werden gegenwärtig intensiv erforscht. Man hofft auf Eigenschaften zu treffen, die zwischen denen isolierter …
M Manoli, A Collins, S Parsons, A Candini… - Journal of the …, 2008 - ACS Publications
The syntheses and structures of two decametallic mixed-valent Mn supertetrahedra using 2- amino-2-methyl-1, 3-propanediol (ampH2), two decametallic mixed-valent Mn planar discs …
The reaction of (NBu n 4)[Mn8O6Cl6 (O2CPh) 7 (H2O) 2](1) with 2-(hydroxymethyl) pyridine (hmpH) or 2-(hydroxyethyl) pyridine (hepH) gives the MnII2MnIII10 title compounds …
M del Carmen Giménez-López, F Moro… - Nature …, 2011 - nature.com
Next-generation electronic, photonic or spintronic devices will be based on nanoscale functional units, such as quantum dots, isolated spin centres or single-molecule magnets …