The air/surface adsorption equilibrium of organic compounds under ambient conditions

KU Goss - Critical Reviews in Environmental Science and …, 2004 - Taylor & Francis
The environmental fate of volatile and semivolatile organic pollutants strongly depends on
their partitioning between the gas phase and condensed phases. This partitioning includes …

Applications of the octanol–air partitioning ratio: a critical review

S Baskaran, F Wania - Environmental Science: Atmospheres, 2023 - pubs.rsc.org
The octanol–air partition ratio (KOA), also referred to as the octanol–air partition coefficient,
has a wide range of applications in environmental chemistry. In this review, we explore the …

Anion effects on gas solubility in ionic liquids

JL Anthony, JL Anderson, EJ Maginn… - The Journal of …, 2005 - ACS Publications
This work presents the results of solubility measurements for a series of gases in 1-n-butyl-3-
methyl imidazolium tetrafluoroborate and 1-n-butyl-3-methyl imidazolium bis …

Solubilities and Thermodynamic Properties of Gases in the Ionic Liquid 1-n-Butyl-3-methylimidazolium Hexafluorophosphate

JL Anthony, EJ Maginn… - The Journal of Physical …, 2002 - ACS Publications
This work presents the solubility of nine different gases in 1-n-butyl-3-methylimidazolium
hexafluorophosphate. The gases considered include carbon dioxide, ethylene, ethane …

Solution thermodynamics of imidazolium-based ionic liquids and water

JL Anthony, EJ Maginn… - The Journal of Physical …, 2001 - ACS Publications
This work presents the vapor− liquid equilibrium and the liquid− liquid equilibrium phase
behavior and associated thermodynamic properties of water with three ionic liquids: 1-n …

Vapor− liquid equilibria by UNIFAC group contribution. 6. Revision and extension

R Wittig, J Lohmann, J Gmehling - Industrial & engineering …, 2003 - ACS Publications
The group contribution method UNIFAC has become very popular because of its large range
of applicability and its reliable predictions of vapor− liquid equilibria. With the help of new …

COSMOSPACE: Alternative to conventional activity‐coefficient models

A Klamt, GJP Krooshof, R Taylor - AIChE journal, 2002 - Wiley Online Library
An analytical solution, COSMOSPACE, to the statistical thermodynamics of a model of
pairwise interacting surfaces, is presented. This solution was initially developed for the a …

Mixed hydrates of methane and water‐soluble hydrocarbons modeling of empirical results

RM De Deugd, MD Jager, J de Swaan Arons - AIChE journal, 2001 - Wiley Online Library
The hydrate disappearance conditions (H− Lw− V→ Lw− V transition) in the water–methane–
water‐soluble hydrocarbon system were measured and modeled. The hydrocarbons in the …

Compilation and correlation of limiting activity coefficients of nonelectrolytes in water

SR Sherman, DB Trampe, DM Bush… - Industrial & …, 1996 - ACS Publications
The phase equilibria of dilute aqueous solutions are treated separately from those of dilute
organic systems due to water's unique structure and hydrogen-bonding characteristics. As a …

Revision of MOSCED parameters and extension to solid solubility calculations

MJ Lazzaroni, D Bush, CA Eckert… - Industrial & …, 2005 - ACS Publications
New pure component parameters are presented for the MOSCED limiting activity coefficient
model for 133 solvents with an absolute average deviation of 10.6% to experimental …