From its earliest observation as an unusual reaction only a half century ago, 1 the insertion
of a carbene into a carbonrhydrogen bond has attracted considerable interest because of its …

Organic chemists have always been fascinated by the cyclopropane subunit. 1 The smallest
cycloalkane is found as a basic structural element in a wide range of naturally occurring …

Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most
important catalytic asymmetric reactions known today This book covers the preparation of …

Conspectus Fluorine-containing cyclopropanes are a subclass of cyclopropane derivatives
that have generated considerable interest in medicinal chemistry for several decades. The …

The rhodium N-(arylsulfonyl) prolinate catalyzed decomposition of vinyldiazomethanes in
the presence of alkenes leads to a very general method for the synthesis of functionalized …

Homogeneous catalysis has been responsible for many major recent developments in
synthetic organic chemistry. The combined use of organometallic and coordination …

The metal‐catalyzed decomposition of diazo compounds in the presence of alkenes is a
well‐established reaction. Since the original Organic Reactions review on the reaction of …

Carboxylate and carboxamide ligands on dirhodium (II) catalysts can provide enormous
regiocontrol in carbon-hydrogen insertion reactions of diazoacetate esters. Whereas 2, 3, 4 …

The transition metal catalyzed reaction of α‐diazo carbonyl compounds has found numerous
applications in organic synthesis, and its use in either heterocyclic or carbocyclic ring …

Carboxylate and carboxamide ligands of dirhodium (II) catalysts control chemoselectivity in
competitive metal carbene transformations of diazo compounds. For competitive …