Main modern approaches to the topological representation of crystal structures of different
chemical classes are overviewed. The problem of automated generation and analysis of …

Key challenges in modern synthetic chemistry include the design of reliable, selective, and
more sustainable synthetic methods, as well as the development of promising candidates for …

Homoleptic cyanide compounds exist of almost all main group elements. While the alkali
metals and alkaline earth metals form cyanide salts, the cyanides of the lighter main group …

Metal thiocyanates were some of the first pseudohalide compounds to be discovered and
adopt a diverse range of structures. This review describes the structures, properties, and …

Although pure hydrogen cyanide can spontaneously polymerize or even explode, when
initiated by small amounts of bases (eg CN−), the reaction of liquid HCN with [WCC] CN …

The trapping of classical hydrogen pseudohalides (HX, X= pseudohalogen= CN, N3, NCO,
NCS, and PCO) utilizing a phosphorus-centered cyclic biradicaloid,[P (μ-NTer)] 2, is …

Within the second funding period of the SPP 1708 “Material Synthesis near Room
Temperature”, which started in 2017, we were able to synthesize novel anionic species …

In the presence of μ-nitridobis (triphenylphosphonium) cation,[PPN]+, it was possible to
stabilize and isolate [PPN]+-salts bearing the highly labile hydrogen cyanide aggregate …

Obwohl reiner Cyanwasserstoff spontan polymerisieren oder sogar explodieren kann, was
durch geringe Mengen an Basen (z. B. CN−) ausgelöst wird, wurde die Reaktion von …

In der vorliegenden Dissertation werden die Ergebnisse der Untersuchungen zur Synthese
und Reaktivität von Salzen mit neuen pseudohalogenidhaltigen Anionen sowie deren …