Solid-state NMR: Methods for biological solids

S Ahlawat, KR Mote, NA Lakomek… - Chemical Reviews, 2022 - ACS Publications
In the last two decades, solid-state nuclear magnetic resonance (ssNMR) spectroscopy has
transformed from a spectroscopic technique investigating small molecules and industrial …

Five decades of homonuclear dipolar decoupling in solid-state NMR: Status and outlook

KR Mote, V Agarwal, PK Madhu - Progress in nuclear magnetic resonance …, 2016 - Elsevier
It has been slightly more than fifty years since the first homonuclear spin decoupling
scheme, Lee-Goldburg decoupling, was proposed for removing homonuclear dipolar …

Exploiting heterogeneous time scale of dynamics to enhance 2D HETCOR solid-state NMR sensitivity

R Zhang, Y Nishiyama, A Ramamoorthy - Journal of Magnetic Resonance, 2019 - Elsevier
Multidimensional solid-state NMR spectroscopy plays a significant role in offering atomic-
level insights into molecular systems. In particular, heteronuclear chemical shift correlation …

A Novel Synthesis of Soluble, Stable Derivatives of the Perchlorinated Trityl Radical

RJ Bushby - European Journal of Organic Chemistry, 2024 - Wiley Online Library
A new approach to the synthesis of derivatives of the perchlorinated tritryl radical is
described. It relies on the fact that, under the conditions required to fully chlorinate the ortho …

Deciphering the Conformations of Glutathione Oxidized Peptide: A Comparative NMR Study in Solution and Solid‐State Environments

DK Senapati, JR Yarava… - Magnetic …, 2025 - Wiley Online Library
Glutathione (GSH) and its oxidized dimer (GSSG) play an important role in living systems as
an antioxidant, balancing the presence of reactive oxygen species (ROS). The central thiol …

Conformational investigation of peptides using solid‐state NMR spectroscopy—A study of polymorphism of β‐turn peptides containing diprolines

JR Yarava, Y Nishiyama, S Raghothama… - Chemical Biology & …, 2020 - Wiley Online Library
The construction of complex protein folds relies on the precise conversion of a linear
polypeptide chain into a compact 3‐dimensional structure. In this context, study of isolated …

[PDF][PDF] Methods to Aid Robust Structural Characterisation Using Nuclear Magnetic Resonance Spectroscopy

C EVANS - 2023 - etheses.dur.ac.uk
The structural assignment of organic molecules in spectroscopy underpins our
understanding of their related physical and chemical properties. This is particularly …

Use of reverse cross-polarization for editing solid–state proton NMR spectra

LR Potnuru, JR Yarava, B Pahari… - Journal of Molecular …, 2018 - Elsevier
We present here the use of the cross-polarization-reverse cross-polarization (CP-RCP)
method for editing proton spectra by identifying protons attached exclusively to a nucleus …

Solid-state NMR at natural isotopic abundance for the determination of conformational polymorphism–the case of designed β-turn peptides containing di-prolines

JR Yarava, R Sonti, K Kantharaju… - Chemical …, 2017 - pubs.rsc.org
The proton double quantum–carbon single quantum correlation experiment has been
applied to designed peptides in the solid state in natural isotopic abundance. Analogous to …

Assignment of the 13 C NMR spectrum by correlation to dipolar coupled proton-pairs and estimation of order parameters of a thiophene based liquid crystal

YJ Reddy, KV Ramanathan - Physical Chemistry Chemical Physics, 2015 - pubs.rsc.org
Materials with widely varying molecular topologies and exhibiting liquid crystalline
properties have attracted considerable attention in recent years. 13C NMR spectroscopy is a …