Metal–organic framework glass composites

R Lin, M Chai, Y Zhou, V Chen, TD Bennett… - Chemical Society …, 2023 - pubs.rsc.org
The melting phenomenon in metal–organic frameworks (MOFs) has been recognised as
one of the fourth generation MOF paradigm behaviours. Molten MOFs have high …

Hierarchical metal‐organic network‐forming glasses toward applications

YS Wei, CW Ashling, T Watcharatpong… - Advanced Functional …, 2023 - Wiley Online Library
Glassy states of network‐forming coordination polymers (CPs) and metal‐organic
frameworks (MOFs) represent a novel category of amorphous materials. Recent years have …

[HTML][HTML] Exploration of glassy state in Prussian blue analogues

N Ma, R Ohtani, HM Le, SS Sørensen… - Nature …, 2022 - nature.com
Prussian blue analogues (PBAs) are archetypes of microporous coordination
polymers/metal–organic frameworks whose versatile composition allows for diverse …

[HTML][HTML] Unconventional mechanical and thermal behaviours of MOF CALF-20

D Fan, S Naskar, G Maurin - Nature Communications, 2024 - nature.com
CALF-20 was recently identified as a benchmark sorbent for CO2 capture at the industrial
scale, however comprehensive atomistic insight into its mechanical/thermal properties under …

Exceptional microscale plasticity in amorphous aluminum oxide at room temperature

EJ Frankberg, A Lambai, J Zhang, J Kalikka… - Advanced …, 2023 - Wiley Online Library
Oxide glasses are an elementary group of materials in modern society, but brittleness limits
their wider usability at room temperature. As an exception to the rule, amorphous aluminum …

[HTML][HTML] In situ micropillar compression of an anisotropic metal-organic framework single crystal

Z Zeng, Y Xiao, JM Wheeler, JC Tan - Communications Chemistry, 2023 - nature.com
Understanding of the complex mechanical behavior of metal-organic frameworks (MOF)
beyond their elastic limit will allow the design of real-world applications in chemical …

Glass and liquid chemistry of coordination polymers and MOFs

S Horike - Bulletin of the Chemical Society of Japan, 2023 - academic.oup.com
The chemistry of coordination polymers and metal-organic frameworks (MOFs) has
progressed largely with the development of crystallography. The study of “disordered …

Multi‐stage Transformations of a Cluster‐Based Metal‐Organic Framework: Perturbing Crystals to Glass‐Forming Liquids that Re‐Crystallize at High Temperature

MZ Chen, J Li, S Liao, YH Guo, T Liu, RF Ma… - Angewandte …, 2023 - Wiley Online Library
Glassy and liquid state metal–organic frameworks (MOFs) are emerging type of materials
subjected to intense research for their rich physical and chemical properties. In this report …

Insights into solid-to-solid transformation of MOF amorphous phases

YA Mezenov, S Bruyere, A Krasilin… - Inorganic …, 2022 - ACS Publications
Metal–organic frameworks (MOFs) have been recently explored as crystalline solids for
conversion into amorphous phases demonstrating non-specific mechanical, catalytic, and …

Network Size Control in Coordination Polymer Glasses and Its Impact on Viscosity and H+ Conductivity

T Ogawa, K Takahashi, T Kurihara… - Chemistry of …, 2022 - ACS Publications
Network structures of glasses are essential to understanding their bulk mechanical and
functional properties. Despite growing interests in coordination polymer (CP) and metal …