Phase separation in supramolecular and covalent adaptable networks

MHP de Heer Kloots, SK Schoustra, JA Dijksman… - Soft Matter, 2023 - pubs.rsc.org
Phase separation phenomena have been studied widely in the field of polymer science, and
were recently also reported for dynamic polymer networks (DPNs). The mechanisms of …

A 3D printed drug delivery implant formed from a dynamic supramolecular polyurethane formulation

S Salimi, Y Wu, MIE Barreiros, AA Natfji, S Khaled… - Polymer …, 2020 - pubs.rsc.org
Using a novel molecular design approach, we have prepared a thermo-responsive
supramolecular polyurethane as a matrix material for use in drug eluting implants. The …

Construction of supramolecular hydrogels using imidazolidinyl urea as hydrogen bonding reinforced factor

J Yu, X Chen, Y Yang, X Zhao, X Chen, T Jing… - Journal of materials …, 2020 - pubs.rsc.org
The development of a new hydrogen bonding reinforced factor is of importance for the
design and application of supramolecular hydrogels. Herein, we use a new reinforced factor …

[HTML][HTML] Thermally and mechanically robust self-healing supramolecular polyurethanes featuring aliphatic amide end caps

AZ Tareq, M Hyder, DH Merino, AM Chippindale… - Polymer, 2024 - Elsevier
A series of supramolecular polyurethanes (SPUs) were designed and synthesised with
synergetic multifunctional hydrogen bonding aliphatic amide end-caps. Hydrogen bonding …

Thermal stimuli response diphenylmethane diisocyanate‐based polyurethane elastomer via adjustable silicon‐induced distinctive microstructure

Y Fang, A Jiang, J Huang… - Polymer Engineering & …, 2024 - Wiley Online Library
The segment character of polyurethanes (PUs) determines the micromorphology and
properties. The effective segment regulation can customize the favorable performance of …

[HTML][HTML] Tailoring viscoelastic properties of dynamic supramolecular poly (butadiene)-based elastomers

M Hyder, AD O'Donnell, AM Chippindale… - Materials Today …, 2022 - Elsevier
The discovery and development of new adhesive materials is critical for real-world
applications of polymeric composite materials. Herein, we report the design and synthesis of …

A modular strategy for fabrication of responsive nanocomposites using functionalized oligocaprolactones and hydroxyapatite nanoparticles

M Sadat-Shojai, S Ghadiri-Ghalenazeri - New Journal of Chemistry, 2020 - pubs.rsc.org
With the intention of mimicking the chemical structure of native bone, many researchers
have emphasized the incorporation of hydroxyapatite (HA) into conventional biopolymers to …

Mechanical characterisation and modelling of a thermoreversible superamolecular polyurethane over a wide range of rates

H Chen, LR Hart, W Hayes, CR Siviour - Polymer, 2021 - Elsevier
Understanding the mechanical response of thermo-recoverable elastomers to applied
deformation at different strain rates and temperatures is crucial for more effective exploitation …

Design and synthesis of aliphatic supramolecular polymers featuring amide, urethane, and urea hydrogen bonding units

AZ Tareq, M Hyder, DH Merino, SD Mohan… - European Polymer …, 2025 - Elsevier
Functionalisation of polyurethane-urea oligomers with hydrogen bonding amide end groups
leads to dramatic thermal, mechanical, morphological, and rheological changes of …

The effect of chiral end groups on the assembly of supramolecular polyurethanes

D Hermida-Merino, LR Hart, PJ Harris, AT Slark… - Polymer …, 2021 - pubs.rsc.org
The ability to influence the physical properties of supramolecular polymers has been the
subject of numerous synthetic studies in recent years. Tuning properties by adjustment of the …