[HTML][HTML] Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments
Replacing fossil fuels with energy sources and carriers that are sustainable, environmentally
benign, and affordable is amongst the most pressing challenges for future socio-economic …
benign, and affordable is amongst the most pressing challenges for future socio-economic …
Supramolecular coordination cages for artificial photosynthesis and synthetic photocatalysis
Because sunlight is the most abundant energy source on earth, it has huge potential for
practical applications ranging from sustainable energy supply to light driven chemistry. From …
practical applications ranging from sustainable energy supply to light driven chemistry. From …
Free energies of proton-coupled electron transfer reagents and their applications
RG Agarwal, SC Coste, BD Groff, AM Heuer… - Chemical …, 2021 - ACS Publications
We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …
Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …
Designing artificial metalloenzymes by tuning of the environment beyond the primary coordination sphere
Metalloenzymes catalyze a variety of reactions using a limited number of natural amino
acids and metallocofactors. Therefore, the environment beyond the primary coordination …
acids and metallocofactors. Therefore, the environment beyond the primary coordination …
Artificial photosynthesis: opportunities and challenges of molecular catalysts
Molecular catalysis plays an essential role in both natural and artificial photosynthesis (AP).
However, the field of molecular catalysis for AP has gradually declined in recent years …
However, the field of molecular catalysis for AP has gradually declined in recent years …
Using nature's blueprint to expand catalysis with Earth-abundant metals
BACKGROUND Catalysis has had a transformative impact on society, playing a crucial role
in the production of modern materials, medicines, fuels, and chemicals. Precious metals …
in the production of modern materials, medicines, fuels, and chemicals. Precious metals …
Recent developments and perspectives in CdS-based photocatalysts for water splitting
Over the past few years, many approaches have been developed progressively to produce
hydrogen (H2) from water under solar light irradiation. This process of fuel production is …
hydrogen (H2) from water under solar light irradiation. This process of fuel production is …
Solar energy conversion by photosystem II: principles and structures
Photosynthetic water oxidation by Photosystem II (PSII) is a fascinating process because it
sustains life on Earth and serves as a blue print for scalable synthetic catalysts required for …
sustains life on Earth and serves as a blue print for scalable synthetic catalysts required for …
Iron and manganese oxo complexes, oxo wall and beyond
High-valent metal–oxo species with multiply-bonded M–O groups have been proposed as
key intermediates in many biological and abiological catalytic oxidation reactions. These …
key intermediates in many biological and abiological catalytic oxidation reactions. These …