Dimethyl carbonate as a modern green reagent and solvent

F Aricò, P Tundo - Russian Chemical Reviews, 2010 - iopscience.iop.org
Published data on dimethyl carbonate as a safe reagent and solvent in organic synthesis
are generalized and analyzed. The methods of dimethyl carbonate preparation and its use …

[HTML][HTML] Isosorbide and dimethyl carbonate: a green match

F Aricò, P Tundo - Beilstein Journal of Organic Chemistry, 2016 - beilstein-journals.org
In this review the reactivity of the bio-based platform compounds D-sorbitol and isosorbide
with green reagents and solvent dimethyl carbonate (DMC) is reported. Dehydration of D …

Green synthesis of dimethyl isosorbide

P Tundo, F Aricò, G Gauthier, LI Rossi, AE Rosamilia… - 2010 - ri.conicet.gov.ar
A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in
the presence of a base is reported. The easy methylation of isosorbide may be due to its …

Facile Cu (I)-catalyzed oxidative coupling of anilines to azo compounds and hydrazines with diaziridinone under mild conditions

Y Zhu, Y Shi - Organic letters, 2013 - ACS Publications
A mild and highly efficient Cu (I)-catalyzed oxidative coupling of anilines is described.
Various primary and secondary anilines can be efficiently coupled under mild conditions to …

One-pot synthesis of bio-based polycarbonates from dimethyl carbonate and isosorbide under metal-free condition

W Fang, Z Zhang, Z Yang, Y Zhang, F Xu, C Li, H An… - Green …, 2020 - pubs.rsc.org
Synthesis of bioderived high-molecular-weight polycarbonates under metal-free condition is
particularly challenging. Here, a green synthetic strategy of bio-based poly (isosorbide …

Acid-catalysed reactions of amines with dimethyl carbonate

P Worsawat, P Noppawan, C Croise… - Organic & …, 2023 - pubs.rsc.org
Highly effective acid-catalysed reactions of amines with dimethyl carbonate (DMC) have
been conducted with significant yields and selectivity of carboxymethylation or methylation …

Synthesis of five‐membered cyclic ethers by reaction of 1, 4‐diols with dimethyl carbonate

F Aricò, P Tundo, A Maranzana, G Tonachini - ChemSusChem, 2012 - Wiley Online Library
Abstract The reaction of 1, 4‐diols with dimethyl carbonate in the presence of a base led to
selective and high‐yielding syntheses of related five‐membered cyclic ethers. This synthetic …

Unexpected formation of N′-phenyl-thiophosphorohydrazidic acid O,S-dimethyl ester from acephate: chemical, biotechnical and computational study

V Kumar, S Kaur, S Singh, N Upadhyay - 3 Biotech, 2016 - Springer
By the nucleophilic attack of phenylhydrazine on acephate in aqueous medium, a stable
product N′-phenyl-thiophosphorohydrazidic acid O, S-dimethyl ester (1) was obtained and …

Reaction Pathways in Carbonates and Esters

P Tundo, F Arico - ChemSusChem, 2023 - Wiley Online Library
This review reports on the competition/collaboration among intertwined base‐catalyzed acyl
cleavage bimolecular mechanism (BAc2)/base‐catalyzed alkyl cleavage bimolecular …

Intramolecular etherification of five-membered cyclic carbonates bearing hydroxyalkyl groups

KM Tomczyk, PA Guńka, PG Parzuchowski… - Green …, 2012 - pubs.rsc.org
We report a new one-pot synthetic route to tetrahydrofuran derivatives, which were
unexpectedly produced under basic conditions by intramolecular etherification of substituted …