Tropospheric OH and HO 2 radicals: field measurements and model comparisons
The hydroxyl radical, OH, initiates the removal of the majority of trace gases in the
atmosphere, and together with the closely coupled species, the hydroperoxy radical, HO2, is …
atmosphere, and together with the closely coupled species, the hydroperoxy radical, HO2, is …
Atmospheric composition change–global and regional air quality
Air quality transcends all scales with in the atmosphere from the local to the global with
handovers and feedbacks at each scale interaction. Air quality has manifold effects on …
handovers and feedbacks at each scale interaction. Air quality has manifold effects on …
The MCM v3. 3.1 degradation scheme for isoprene
ME Jenkin, JC Young, AR Rickard - Atmospheric Chemistry and …, 2015 - acp.copernicus.org
The chemistry of isoprene degradation in the Master Chemical Mechanism (MCM) has been
systematically refined and updated to reflect recent advances in understanding, with these …
systematically refined and updated to reflect recent advances in understanding, with these …
Radical chemistry at a rural site (Wangdu) in the North China Plain: observation and model calculations of OH, HO2 and RO2 radicals
A comprehensive field campaign was carried out in summer 2014 in Wangdu, located in the
North China Plain. A month of continuous OH, HO 2 and RO 2 measurements was achieved …
North China Plain. A month of continuous OH, HO 2 and RO 2 measurements was achieved …
The molecular identification of organic compounds in the atmosphere: state of the art and challenges
The Earth's atmosphere offers a striking contrast with other known planets by its rich organic
composition, which results almost exclusively from the presence of life on the planet. About …
composition, which results almost exclusively from the presence of life on the planet. About …
Atmospheric oxidation capacity sustained by a tropical forest
Terrestrial vegetation, especially tropical rain forest, releases vast quantities of volatile
organic compounds (VOCs) to the atmosphere,,, which are removed by oxidation reactions …
organic compounds (VOCs) to the atmosphere,,, which are removed by oxidation reactions …
Amplified trace gas removal in the troposphere
A Hofzumahaus, F Rohrer, K Lu, B Bohn, T Brauers… - science, 2009 - science.org
The degradation of trace gases and pollutants in the troposphere is dominated by their
reaction with hydroxyl radicals (OH). The importance of OH rests on its high reactivity, its …
reaction with hydroxyl radicals (OH). The importance of OH rests on its high reactivity, its …
Ozone and organic nitrates over the eastern United States: Sensitivity to isoprene chemistry
We implement a new isoprene oxidation mechanism in a global 3‐D chemical transport
model (GEOS‐Chem). Model results are evaluated with observations for ozone, isoprene …
model (GEOS‐Chem). Model results are evaluated with observations for ozone, isoprene …
Hydroxyl radical recycling in isoprene oxidation driven by hydrogen bonding and hydrogen tunneling: The upgraded LIM1 mechanism
J Peeters, JF Müller, T Stavrakou… - The Journal of Physical …, 2014 - ACS Publications
The Leuven isoprene mechanism, proposed earlier to aid in rationalizing the unexpectedly
high hydroxyl radical (OH) concentrations in isoprene-rich, low-nitric-oxide (NO) regions …
high hydroxyl radical (OH) concentrations in isoprene-rich, low-nitric-oxide (NO) regions …
Measurement of OH and HO2 in the Troposphere
DE Heard, MJ Pilling - Chemical reviews, 2003 - ACS Publications
Volatile organic compounds (VOCs), emitted into the atmosphere, react with a range of
oxidants, of which the most important are OH, NO3, and ozone. Under most atmospheric …
oxidants, of which the most important are OH, NO3, and ozone. Under most atmospheric …