Polyoxometalates (POMs), a kind of molecular metal oxide cluster with unique physical–
chemical properties, have made essential contributions to creating efficient and robust …

Conspectus Noble metal catalysts, in particular palladium-containing materials, are of prime
commercial interest, because of their role as oxidation catalysts in automobile emission …

Nanoscale inorganic wheel-shaped structures are one of the most striking types of
molecular aggregations. Here, we report the synthesis of a gigantic lanthanide wheel cluster …

Crystallization at the solid–liquid interface is difficult to spectroscopically observe and
therefore challenging to understand and ultimately control at the molecular level. The Ce70 …

Polyoxopalladates (POPs) are a class of self‐assembling palladium‐oxide clusters that span
a variety of sizes, shapes and compositions. The largest of this family,{Pd84} Ac, is …

New members of the Mn70 and Mn84 torus-like cluster family have been prepared from a
hybrid comproportionation–alcoholysis reaction of [Mn12O12 (O2CR) 16 (H2O) 4] in alcohol …

Herein, we report the discovery of a toroidal inorganic cluster of zirconium (IV) oxysulfate of
unprecedented size with the formula Zr70 (SO4) 58 (O/OH) 146⋅ x (H2O)(Zr70), which …

Nature creates exquisite molecular assemblies, required for the molecular-level functions of
life, via self-assembly. Understanding and harnessing these complex processes presents an …

Polyoxometalate (POM) macrocycles have been extensively investigated due to their
potential applications in various fields, including sensing, optics, magnetism, proton …

Polyoxometalates (POMs) are an intriguing class of compounds due to their tremendous
structural variety and the wide spectrum of resulting properties, which make them interesting …