Reactions catalyzed within porous inorganic and organic materials and at electrochemical
interfaces commonly occur at high coverage and in condensed media, causing turnover …

Hydration free energies are dictated by a subtle balance of hydrophobic and hydrophilic
interactions. We present here a spectroscopic approach, which gives direct access to the …

An aqueous electrochemically controlled host–guest encapsulation system demonstrates a
large and synthetically tunable redox entropy change. Electrochemical entropy is the basis …

Hydrophobicity/hydrophilicity of aqueous interfaces at the molecular level results from a
subtle balance in the water–water and water–surface interactions. This is characterized here …

The results of quantum chemical and molecular dynamics calculations reveal that
polyanionic gallium-based cages accelerate cyclization reactions of pentadienyl alcohols as …

Polycyclic aromatic hydrocarbons (PAHs) find multiple applications ranging from fabric dyes
to optoelectronic materials. Hydrogenation of PAHs is often employed for their purification or …

Spatial orderliness, which is the orderly structure of molecules, differs significantly between
interfacial water and bulk water. Understanding this property is essential for various …

Acid–base reactions are ubiquitous in solution chemistry, as well as in electrochemistry.
However, macroscopic concepts derived in solutions, such as p K a and pH, differ …

In enzymes, protein residues themselves carry charges and produce a preorganized local
electric field (LEF). Such LEFs can be modified by strategically mutating the charged and …

The realm of catalytic chemistry has witnessed notable advancements through the
integration of photoredox confined synergistic catalysis, a method that synergizes the …