Conspectus Transition metal-catalyzed carbonylation reactions represent a direct and atom-
economical approach to introduce oxygen functionality into organic compounds, with CO …

Transition metal-catalysed cross-coupling reactions are widely used for construction of
carbon–carbon and carbon–heteroatom bonds. However, compared to aryl or alkenyl …

The nickel-catalyzed multicomponent dicarbofunctionalization of alkenes represents one of
the most straightforward approaches to complex organofluorine compounds. However, the …

Radical single carbonylation reactions with CO constitute a direct and robust strategy toward
various carbonyl compounds from readily available chemicals, and have been extensively …

Carbonylation reactions involving CO as readily available C1 synthons have become one of
the most important tools for the construction of carbonyl compounds from feedstock …

Transition-metal-catalyzed carbonylation is one of the most straightforward strategies to
prepare carbonyl compounds. However, compared to well-established noble-metal …

Carbon monoxide is a cheap and abundant C1 building block that can be readily
incorporated into organic molecules to rapidly build structural complexity. In this Perspective …

In the last few decades, photocatalytic radical carbonylation strategies have received
considerable attention as they are becoming a formidable tool in the toolbox of organic …

Visible-light photoredox catalysis has attracted tremendous interest within the synthetic
community. As such, the activation mode potentially provides a more sustainable and …

Acyl radicals have been generated from α-keto acids using inexpensive and commercially
available 2-chloro-thioxanthen-9-one as the photoredox catalyst under visible light …