The design and implementation of cascade reactions is a challenging facet of organic
chemistry, yet one that can impart striking novelty, elegance, and efficiency to synthetic …

Asymmetric catalysis with transition‐metal complexes is the basis for a vast array of
stereoselective transformations and has changed the face of modern synthetic chemistry …

Herein, we report a synthesis of cyclohexanones bearing multi‐continuous stereocenters by
combining copper‐catalyzed asymmetric conjugate addition of dialkylzinc reagents to cyclic …

The current status of organic synthesis is hampered by costly protecting‐group strategies
and lengthy purification procedures after each synthetic step. To circumvent these problems …

An efficient method for the diastereo‐and enantioselective construction of vicinal all‐carbon
quaternary stereocenters through palladium‐catalyzed decarboxylative cycloaddition of …

Abstract Die Entwicklung und Umsetzung von Kaskadenreaktionen hat zu beachtlichen
neuartigen, eleganten und effizienten Synthesestrategien geführt. Als besonders …

Der derzeitige Stand der organischen Synthese macht oft kostspielige
Schutzgruppenstrategien und aufwändige Reinigungsschritte nach jeder Synthesestufe …

Catalytic asymmetric synthesis is providing chemists with new and powerful tools for the
efficient synthesis of complex molecules.[1] Although for many years asymmetric catalysis …

A new metal‐free oxidative radical [2+ 2+ 1] carbocyclization of benzene‐linked 1, n‐enynes
with two C (sp3) H bonds adjacent to the same heteroatom is described. This method …

The discovery of new strategies that emulate nature s capacity to rapidly construct
architectural complexity continues to be a central focus for research and development in the …