The Brookhart-type α-diimine nickel and palladium catalysts are one of the most examined
systems in the field of olefin polymerization. Even after more than twenty years of extensive …

Abstract α-Diimine Ni and Pd complexes are one of the most examined late-transition
organometallics in the application of catalyzed ethylene (co) polymerization. These …

Homogeneous nickel catalysts have a considerable track record for mediating ethylene
chain growth in the form of oligomerization and more recently polymerization. Within the …

The fascination of the well-defined metal catalysts for olefin polymerization is their capability
to control the properties of the polymer such as topology (linear to highly branched), range of …

The aim of designing multinuclear catalysts for olefin polymerization is to have the best
control on the catalyst behavior and final polymer properties. This control is in relation to …

Binuclear olefin polymerization catalysts have recently attracted extensive interest in the
field of polyolefin synthesis due to their excellent catalytic performance. In this work, we …

A series of dinuclear pyridyl‐imine Co‐and Ni‐based complexes (Co: C1 and C2 and Ni: C3
and C4) were prepared in reasonable yields through one‐pot synthesis method. Toward …

Coordinative polymerization brings opportunities for producing well-defined long-chain
branched polyolefins specifically by using homogeneous single-site catalysts. Herein, we …

The bimetallic synergistic strategy has attracted interest and been frequently explored in late-
transition-metal-catalyzed olefin (co) polymerization. In this contribution, a series of bulky o …

A straightforward two-step synthesis of a new family of electronically distinct para-
biphenylene-linked 1, 2-bis (imino) acenaphthene/pyridyl-2-imine (BIAN-PI) ligands, 2 …