Fragmentation of the PAH cations of Isoviolanthrene and Dicoronylene: A case made for interstellar cyclo [n] carbons as products of universal fragmentation processes

HR Hrodmarsson, J Bouwman, AGGM Tielens… - International Journal of …, 2023 - Elsevier
The photo-induced fragmentation pathways of the cationic forms of isoviolanthrene (C 34 H
18) and dicoronylene (C 48 H 20) are systematically studied with mass spectrometry …

Probing colossal carbon rings

SJP Marlton, JT Buntine, P Watkins, C Liu… - The Journal of …, 2023 - ACS Publications
Carbon aggregates containing between 10 and 30 atoms preferentially arrange themselves
as planar rings. To learn more about this exotic allotrope of carbon, electronic spectra are …

The EDIBLES survey-VII. A survey of C2 and C3 in interstellar clouds

H Fan, CMR Rocha, M Cordiner, H Linnartz… - Astronomy & …, 2024 - aanda.org
Context. Small linear carbon chain radicals such as C 2 and C 3 act as both the building
blocks and dissociation fragments of larger carbonaceous species. Their rotational …

Disentangling Electronic Spectra of Linear and Cyclic Hydrogenated Carbon Cluster Cations, C2n+1H+ (n = 3–10)

SJP Marlton, JT Buntine, C Liu, P Watkins… - The Journal of …, 2022 - ACS Publications
Electronic spectra are measured for protonated carbon clusters (C2 n+ 1H+) containing
between 7 and 21 carbon atoms. Linear and cyclic C2 n+ 1H+ isomers are separated and …

New light on the imbroglio surrounding the C 8 H+ 6 isomers formed from ionized azulene and naphthalene using ion–molecule reactions

C Rossi, G Muller, R Thissen, C Romanzin… - Chemical …, 2024 - pubs.rsc.org
Most polycyclic aromatic hydrocarbons (PAHs) can isomerize with internal energies near to
or below the dissociation threshold. The C10H+ 8 group of ions, made up of the …

Photoprocessing of cationic triazacoronene: dissociation characteristics of polycyclic aromatic nitrogen heterocycles in interstellar environments

D Schleier, J Kamer, A Jiao, GF Schneider… - Physical Chemistry …, 2024 - pubs.rsc.org
Polycyclic aromatic nitrogen heterocycles (PANHs) are present in various astronomical
environments where they are subjected to intense radiation. Their photodissociation …

Extended correlations between diffuse interstellar bands

A Omont - Astronomy & Astrophysics, 2024 - aanda.org
The systematic analysis of the correlations between diffuse interstellar bands (DIBs) is
extended to weak DIBs through the comprehensive catalogue of the Apache Peak …

Impact Ionization Mass Spectra of Polypyrrole-Coated Anthracene Microparticles: A Useful Mimic for Cosmic Polycyclic Aromatic Hydrocarbon Dust

R Mikula, Z Sternovsky, SP Armes, E Ayari… - ACS Earth and Space …, 2024 - ACS Publications
Polycyclic aromatic hydrocarbons (PAHs) are abundantly present in the interstellar medium
and in our solar system and lock up a significant fraction of cosmic carbon. They are found to …

Laser-induced fragmentation of coronene cations

S Panchagnula, J Kamer, A Candian… - Physical Chemistry …, 2024 - pubs.rsc.org
Polycyclic aromatic hydrocarbons are an important component of the interstellar medium of
galaxies and photochemistry plays a key role in the evolution of these species in space …

Photofragmentation of corannulene (C 20 H 10) and sumanene (C 21 H 12) cations in the gas phase and their astrophysical implications

P Sundararajan, A Candian, J Kamer… - Physical Chemistry …, 2024 - pubs.rsc.org
Aromatic infrared bands (AIBs) dominate the mid-infrared spectra of many galactic and
extragalactic sources. These AIBs are generally attributed to fluorescence emission from …