While β-diketiminate (BDI or 'nacnac') ligands have been widely adopted to stabilize a wide
range of metal ions in multiple oxidation states and coordination numbers, in several …

The characteristic ligation properties of different β-diketiminato ligands (often called
“nacnac”) in group 13 metal complexes are well studied via preparation, characterization …

The coordination chemistry of the {RuCp*}+ fragment was studied toward several 4, 5-
diazafluorene derivatives. The ambidentate nature of these 4, 5-diazafluorene derivatives …

Treatment of the appropriate lithium or sodium 2, 4-N, N′-disubstituted 1, 3, 5-
triazapentadienate [RNC (R′) NC (R′) N (SiMe3) M] 2 (R= Ph, 2, 6-i Pr2− C6H3 (Dipp) or …

Palladium (II) complexes with a bidentate, anionic formazanate ligand are described.
Attempts to prepare mono (formazanate) palladium alkyl complexes often leads to the …

Here we report the synthesis and characterization of a series of palladium β-diiminate
complexes. Chloro-bridged dimers [Pd (Ar2nacnac)(μ-Cl)] 2 (where [Ar2nacnac]− is [(ArNC …

The controlled synthesis of isomeric organoplatinum clamshell dimers [Pt2Me2 (μ2-κ3-6-
dppd) 2] 2+, 6-dppd= 1, 4-di-2-pyridyl-5, 6, 7, 8, 9, 10-hexahydrocycloocta [d] pyridazine, is …

The (β‐ketiminato) rhodium complex [Rh {κ2‐(N, O)‐(tBu)(O) CCHC (tBu) N
(C6F5)}(cod)](1)[cod=(1Z, 5Z)‐1, 5‐cyclooctadiene] and (β‐diketiminato) rhodium …

Palladium (II) complexes with a bidentate, anionic formazanate ligand are described.
Attempts to prepare mono (formazanate) palladium alkyl complexes often leads to the …

Throughout this thesis, we study the coordination chemistry of the redox active formazanate
ligands to iron and palladium and we explore the (catalytic) reactivity of the resulting …