N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …

Metal–organic frameworks (MOFs), established as a relatively new class of crystalline
porous materials with high surface area, structural diversity, and tailorability, attract …

More than 1000× uranium exists in the oceans than exists in terrestrial ores. With nuclear
power generation expected to increase over the coming decades, access to this …

Transition metal (TM) catalyzed cross-coupling reactions are the utmost versatile and
reliable methods for the production of many industrially important fine chemicals. The …

Palladium (Pd) has been the key element for several C–C bond-forming reactions,
especially the Nobel-acclaimed Suzuki, Heck, and Sonogashira cross-coupling reactions …

In the present review, we consider the transformations of molecular catalysts, leaching,
aggregation and various interconversions of metal complexes, clusters and nanoparticles …

The potential of operando X-ray techniques for following the structure, fate, and active site of
single-atom catalysts (SACs) is highlighted with emphasis on a synergetic approach of both …

This review describes the recent advances in understanding of the mechanism of palladium
catalyzed C–C cross-coupling reactions. The discussion is focused on the role of palladium …

Metal organic frameworks (MOFs) are one set of the most excellent supports for Pd
nanoparticles (NPs). MOFs as the host mainly have the following advantages:(i) they provide …

We reported herein a strategy for combining CUS-based MOF (CUS= coordinatively
unsaturated metal sites) with ionic liquid (IL) functional sites to form bifunctional …